Enhancing the ambient stability of few-layer black phosphorus by surface modification
文献类型：期刊论文
| 作者 | Lei, Shuang-Ying; Shen, Hai-Yun; Sun, Yi-Yang; Wan, Neng; Yu, Hong; Zhang, Shengbai2 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2018 |
| 卷号 | 8期号:26页码:14676 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c8ra00560e |
| 英文摘要 | Based on high-throughput density functional theory calculations, we investigated the adsorption characteristics of various elements across the Periodic Table on few-layer black phosphorus (BP). Using the criterion that the ratio of adsorption energy (E-ads) to bulk cohesive energy (E-coh) is greater than one (E-ads/E-coh > 1), we selected fifteen elements. The adsorption of these elements on few-layer BPs could significantly shift their conduction-band minimum (CBM) downward, suggesting the possibility of preventing the few-layer BPs from oxidation if the CBM can be shifted below the O-2/O-2(-) redox potential. Our study offers an efficient approach to overcoming the technical barrier in the practical application of few-layer BPs by enhancing its ambient stability via surface modification. |
| 学科主题 | Chemistry, Multidisciplinary |
| WOS记录号 | WOS:000430536600060 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | This work was supported by the National Science Foundation of Jiangsu Province of China (No. BK20151409), the National Basic Research Program of China (No. 2015CB352100), and the National Natural Science Foundation of China (No. 11774052, 61771137, 61370042, 11674053). The authors would like to acknowledge Shanghai Supercomputer Center. ; This work was supported by the National Science Foundation of Jiangsu Province of China (No. BK20151409), the National Basic Research Program of China (No. 2015CB352100), and the National Natural Science Foundation of China (No. 11774052, 61771137, 61370042, 11674053). The authors would like to acknowledge Shanghai Supercomputer Center. |
| 源URL | [http://ir.sic.ac.cn/handle/331005/24576]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 作者单位 | 1.Southeast Univ, Minist Educ, Key Lab Microelectromech Syst, Nanjing 210096, Jiangsu, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 201899, Peoples R China 3.Rensselaer Polytech Inst, Dept Phys Appl Phys & Astron, Troy, NY 12180 USA |
| 推荐引用方式 GB/T 7714 | Lei, Shuang-Ying,Shen, Hai-Yun,Sun, Yi-Yang,et al. Enhancing the ambient stability of few-layer black phosphorus by surface modification[J]. RSC ADVANCES,2018,8(26):14676, 14683. |
| APA | Lei, Shuang-Ying,Shen, Hai-Yun,Sun, Yi-Yang,Wan, Neng,Yu, Hong,&Zhang, Shengbai.(2018).Enhancing the ambient stability of few-layer black phosphorus by surface modification.RSC ADVANCES,8(26),14676. |
| MLA | Lei, Shuang-Ying,et al."Enhancing the ambient stability of few-layer black phosphorus by surface modification".RSC ADVANCES 8.26(2018):14676. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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