Dielectric relaxation and phase transition behavior of (1-x)Pb(Zn1/3Nb2/3)O-3-xBaTiO(3) binary solid solutions
文献类型：期刊论文
| 作者 | Gao, Qiang1; Hu, Qingyuan1; Jin, Li1; Gorev, M. V.; Chezganov, D. S.; Vlasov, E. O.; Zeng, Huarong4; Zhao, Luyang1; Cui, Yu1; Xu, Zhuo1 |
| 刊名 | CERAMICS INTERNATIONAL
 |
| 出版日期 | 2018 |
| 卷号 | 44期号:15页码:18491 |
| 关键词 | Dielectric relaxation Phase transition "U"-shaped variation Polarization mismatch |
| ISSN号 | 0272-8842 |
| DOI | 10.1016/j.ceramint.2018.07.069 |
| 英文摘要 | Dielectric relaxation and phase transition behaviors in (1-x)Pb(Zn1/3Nb2/3)O-3-xBaTiO(3) (PZN-BT) binary solid solutions have been systematically studied in this paper. All the compositions display a pure pseudo-cubic perovskite structure. As the BT contents increase from 10 mol% to 70 mol%, the phase transition peak becomes broader and broader, accompanying with decreases of cm (the maximum dielectric permittivity) and T-m (the temperature corresponds to the epsilon(m)). Nevertheless, an abnormal increase of epsilon(m) and T-m occurs when the BT contents exceeds 70 mol%, forming a "U" shaped curve of the compositional dependence of epsilon(m) and T-m. Moreover, it is indicated from the new glass model fitting results that the characteristic parameter p, which represents the degree of relaxation, also shows a similar "U" shaped variation curve. Similarly, as shown in polarization-electric field loops, both remnant polarizations (P-r) and coercive fields (E-c) display the "U" shaped curve as the BT content changes from 10 mol% to 80 mol%. Finally, according to the similar variation of these key parameters mentioned above, a polarization mismatched model, which describes the destruction and reestablishment of the long range order arrangement in solid solutions composed of two kinds of ferroelectrics, is proposed to illustrate the underlying mechanism. In this PZN-BT system or other similar ABO(3)-type perovskite relaxors, the competition between the A-O and B-O coupling plays an important role to form the "U" shaped evolution of these key parameters. |
| 学科主题 | Materials Science, Ceramics |
| WOS记录号 | WOS:000445993000117 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | This work was supported by the National Basic Research Program of China (Grant No. 2015CB654602), the International Science & Technology Cooperation Program of China (Grant No. 2015DFA51100), the NSFC projects (Grant Nos. 51761145024 and 51772239), Shaanxi province project 2017 ktpt-21, the Joint fund of the Ministry of Education (Grant No. 6141A02033210) and the 111 Project under Grant No. B14040. The SEM work was done at International Center for Dielectric Research (ICDR), Xi'an Jiaotong University, Xi'an, China. ; This work was supported by the National Basic Research Program of China (Grant No. 2015CB654602), the International Science & Technology Cooperation Program of China (Grant No. 2015DFA51100), the NSFC projects (Grant Nos. 51761145024 and 51772239), Shaanxi province project 2017 ktpt-21, the Joint fund of the Ministry of Education (Grant No. 6141A02033210) and the 111 Project under Grant No. B14040. The SEM work was done at International Center for Dielectric Research (ICDR), Xi'an Jiaotong University, Xi'an, China. |
| 源URL | [http://ir.sic.ac.cn/handle/331005/24641]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 作者单位 | 1.Xi An Jiao Tong Univ, Elect Mat Res Lab, Key Lab, Minist Educ,Sch Elect & Format Engn, Xian 710049, Shaanxi, Peoples R China 2.Xi An Jiao Tong Univ, Sch Elect & Format Engn, Int Ctr Dielect Res, Xian 710049, Shaanxi, Peoples R China 3.Gorev, M. V.] Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia 4.Gorev, M. V.] Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk 660041, Russia 5.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China 6.Chezganov, D. S.; Vlasov, E. O.] Ural Fed Univ, Sch Nat Sci & Math, Ekaterinburg 620000, Russia |
| 推荐引用方式 GB/T 7714 | Gao, Qiang,Hu, Qingyuan,Jin, Li,et al. Dielectric relaxation and phase transition behavior of (1-x)Pb(Zn1/3Nb2/3)O-3-xBaTiO(3) binary solid solutions[J]. CERAMICS INTERNATIONAL,2018,44(15):18491, 18498. |
| APA | Gao, Qiang.,Hu, Qingyuan.,Jin, Li.,Gorev, M. V..,Chezganov, D. S..,...&Wei, Xiaoyong.(2018).Dielectric relaxation and phase transition behavior of (1-x)Pb(Zn1/3Nb2/3)O-3-xBaTiO(3) binary solid solutions.CERAMICS INTERNATIONAL,44(15),18491. |
| MLA | Gao, Qiang,et al."Dielectric relaxation and phase transition behavior of (1-x)Pb(Zn1/3Nb2/3)O-3-xBaTiO(3) binary solid solutions".CERAMICS INTERNATIONAL 44.15(2018):18491. |
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来源：上海硅酸盐研究所
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