Enhanced Curie temperature and piezoelectric properties of (Ba0.85Ca0.15) (Zr0.10Ti0.90)O-3 lead-free ceramics after the addition of LiTaO3
文献类型:期刊论文
作者 | Zhou, Mingxing1; Liang, Ruihong; Zhou, Zhiyong; Xu, Chenhong1; Nie, Xin1; Dong, Xianlin |
刊名 | MATERIALS RESEARCH BULLETIN
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出版日期 | 2018 |
卷号 | 106页码:213 |
关键词 | Piezoelectric ceramics Electrical properties BCZT Curie temperature Coexisting orthorhombic and tetragonal phase |
ISSN号 | 0025-5408 |
DOI | 10.1016/j.materresbull.2018.05.036 |
英文摘要 | Polycrystalline (Ba0.85Ca0.15)(Zr0.10Ti0.90)O-3-xLiTaO(3) ceramics were designed and synthesized using a solid-state reaction to improve both the Curie temperature and the electrical properties of (Ba0.85Ca0.15)(Zr0.10Ti0.90)O-3 lead-free piezoelectric ceramics. The effect that the addition of LiTaO3 has on the structure and electrical properties of BCZT ceramics was studied systemically. The results show that the Curie temperature and the piezoelectric properties of BCZT can be substantially enhanced by adding LiTaO3. The Curie temperature increased from 93 degrees C to 102 degrees C after adding LT of 0.3 mol.%. X-ray diffraction and Raman spectral analysis of the ceramics reveal the coexistence of orthorhombic (O) and tetragonal (T) phases. This coexistence of O and T phases at room temperature helps improve the ferroelectric and piezoelectric properties. The ceramic with x = 0.3 mol.% exhibits the highest values for d(33) = 433 pC/N, d(33)* = 858 pm/V (at 1 kV/mm) and k(p) = 44.6%. Furthermore, giant electrostrictive coefficients (Q(33) approximate to 0.040-0.050 m(4)/C-2) were also obtained for these LT-doped BCZT ceramics. These properties confirm that BCZT-xLT is a promising candidate system for lead-free piezoelectric ceramic materials. |
学科主题 | Materials Science, Multidisciplinary |
WOS记录号 | WOS:000441491900027 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
资助机构 | This work was supported by the National Natural Science Foundation of China (Grant No. 11574334) and the National Key Basic Research Program of China (973 Program, Grant No. 2015CB057502). ; This work was supported by the National Natural Science Foundation of China (Grant No. 11574334) and the National Key Basic Research Program of China (973 Program, Grant No. 2015CB057502). |
源URL | [http://ir.sic.ac.cn/handle/331005/24653] ![]() |
专题 | 中国科学院上海硅酸盐研究所 |
作者单位 | 1.Chinese Acad Sci, Key Lab Inorgan Funct Mat & Devices, Shanghai Inst Ceram, 1295 Dingxi Rd, Shanghai 200050, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhou, Mingxing,Liang, Ruihong,Zhou, Zhiyong,et al. Enhanced Curie temperature and piezoelectric properties of (Ba0.85Ca0.15) (Zr0.10Ti0.90)O-3 lead-free ceramics after the addition of LiTaO3[J]. MATERIALS RESEARCH BULLETIN,2018,106:213, 219. |
APA | Zhou, Mingxing,Liang, Ruihong,Zhou, Zhiyong,Xu, Chenhong,Nie, Xin,&Dong, Xianlin.(2018).Enhanced Curie temperature and piezoelectric properties of (Ba0.85Ca0.15) (Zr0.10Ti0.90)O-3 lead-free ceramics after the addition of LiTaO3.MATERIALS RESEARCH BULLETIN,106,213. |
MLA | Zhou, Mingxing,et al."Enhanced Curie temperature and piezoelectric properties of (Ba0.85Ca0.15) (Zr0.10Ti0.90)O-3 lead-free ceramics after the addition of LiTaO3".MATERIALS RESEARCH BULLETIN 106(2018):213. |
入库方式: OAI收割
来源:上海硅酸盐研究所
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