Nanoporous CaCO3 Coatings Enabled Uniform Zn Stripping/Plating for Long-Life Zinc Rechargeable Aqueous Batteries
文献类型：期刊论文
| 作者 | Kang, Litao; Cui, Mangwei1; Jiang, Fuyi; Gao, Yanfeng2; Luo, Hongjie2; Liu, Jianjun3; Liang, Wei1; Zhi, Chunyi4 |
| 刊名 | ADVANCED ENERGY MATERIALS
 |
| 出版日期 | 2018 |
| 卷号 | 8期号:25 |
| 关键词 | dendrites metal anodes nanoporous stripping/plating Zn-based batteries |
| ISSN号 | 1614-6832 |
| DOI | 10.1002/aenm.201801090 |
| 英文摘要 | Zn-based batteries are safe, low cost, and environmentally friendly, as well as delivering the highest energy density of all aqueous battery systems. However, the application of Zn-based batteries is being seriously hindered by the uneven electrostripping/electroplating of Zn on the anodes, which always leads to enlarged polarization (capacity fading) or even cell shorting (low cycling stability). How a porous nano-CaCO3 coating can guide uniform and position-selected Zn stripping/plating on the nano-CaCO3-layer/Zn foil interfaces is reported here. This Zn-deposition-guiding ability is mainly ascribed to the porous nature of the nano-CaCO3-layer, since similar functionality (even though relatively inferior) is also found in Zn foils coated with porous acetylene black or nano-SiO2 layers. Furthermore, the potential application of this strategy is demonstrated in Zn vertical bar ZnSO4+MnSO4 vertical bar CNT/MnO2 rechargeable aqueous batteries. Compared with the ones with bare Zn anodes, the battery with a nano-CaCO3-coated Zn anode delivers a 42.7% higher discharge capacity (177 vs 124 mAh g(-1) at 1 A g(-1)) after 1000 cycles. |
| 学科主题 | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
| WOS记录号 | WOS:000443674100012 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | L.-T.K. and M.-W.C. contributed equally to this work. This work was supported by the National Natural Science Foundation of China (NSFC, 51502194, 51772257), the National Key R&D Program of China (2016YFB0303900), the Early Career Scheme of the Research Grants Council of Hong Kong SAR (CityU 9041997), and the Opening Project of State Key Laboratory of High Performance Ceramics and Superfine Microstructure (SKL201511SIC) for financial support. ; L.-T.K. and M.-W.C. contributed equally to this work. This work was supported by the National Natural Science Foundation of China (NSFC, 51502194, 51772257), the National Key R&D Program of China (2016YFB0303900), the Early Career Scheme of the Research Grants Council of Hong Kong SAR (CityU 9041997), and the Opening Project of State Key Laboratory of High Performance Ceramics and Superfine Microstructure (SKL201511SIC) for financial support. |
| 源URL | [http://ir.sic.ac.cn/handle/331005/24679]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 作者单位 | 1.Yantai Univ, Sch Environm & Mat Engn, Yantai 264005, Shandong, Peoples R China 2.Taiyuan Univ Technol TYUT, Coll Mat Sci & Engn, Taiyuan 030024, Shanxi, Peoples R China 3.Shanghai Univ, Sch Mat Sci & Engn, Shanghai 200072, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 201899, Peoples R China 5.City Univ Hong Kong, Dept Phys & Mat Sci, 83 Tat Chee Ave, Hong Kong 999077, Hong Kong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kang, Litao,Cui, Mangwei,Jiang, Fuyi,et al. Nanoporous CaCO3 Coatings Enabled Uniform Zn Stripping/Plating for Long-Life Zinc Rechargeable Aqueous Batteries[J]. ADVANCED ENERGY MATERIALS,2018,8(25). |
| APA | Kang, Litao.,Cui, Mangwei.,Jiang, Fuyi.,Gao, Yanfeng.,Luo, Hongjie.,...&Zhi, Chunyi.(2018).Nanoporous CaCO3 Coatings Enabled Uniform Zn Stripping/Plating for Long-Life Zinc Rechargeable Aqueous Batteries.ADVANCED ENERGY MATERIALS,8(25). |
| MLA | Kang, Litao,et al."Nanoporous CaCO3 Coatings Enabled Uniform Zn Stripping/Plating for Long-Life Zinc Rechargeable Aqueous Batteries".ADVANCED ENERGY MATERIALS 8.25(2018). |
入库方式： OAI收割
来源：上海硅酸盐研究所
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