Structural, spectroscopic and thermal properties of hot-pressed Nd:(Ca0.94Gd0.06)F-2.06 transparent ceramics
文献类型:期刊论文
作者 | Yi, Guoqiang; Li, Weiwei1; Song, Jinghong2; Mei, Bingchu; Zhou, Zhiwei; Su, Liangbi3 |
刊名 | JOURNAL OF THE EUROPEAN CERAMIC SOCIETY |
出版日期 | 2018 |
卷号 | 38期号:9页码:3240 |
ISSN号 | 0955-2219 |
关键词 | Transparent ceramics Neodymium Optical properties Thermal properties |
DOI | 10.1015/j.jeurceramsoc.2018.03.016 |
英文摘要 | 0.5-5.0 at.% Nd3+ doped (Ca(0.94)Gd(0.0)6)F-2.06 transparent ceramics were fabricated by vacuum hot-pressing sintering. The structural, spectroscopic and thermal properties of Nd:(Ca(0.94)Gd(0.0)6)F-2.06 transparent ceramics, as well as the influence of Nd3+ content on these properties were investigated. The as-fabricated ceramic samples exhibited high transparency and nearly pore-free microstructure. The absorption peaks located at 538 nm, 576 nm, 736 nm, 792 nm and 865 nm were attributed to the transitions from ground state to the excited states of Nd3+ ions, and the absorption coefficients increased linearly with Nd3+ content increasing. The emission band of the sample doped with 1 at.% Nd3+ concentration exhibited the highest emission intensity, while the lifetime decreased sharply with the increase of Nd3+ concentration. In addition, with Nd3+ content increasing from 0.5 to 5.0 at.%, the thermal expansivity coefficients increased slightly, while the thermal conductivity decreased from 4.21 to 2.36 W/m K at room temperature. |
学科主题 | Materials Science, Ceramics |
出版者 | ELSEVIER SCI LTD |
WOS记录号 | WOS:000433014200023 |
资助机构 | This work was supported by the National Natural Science Foundation of China (51432007). ; This work was supported by the National Natural Science Foundation of China (51432007). |
源URL | [http://ir.sic.ac.cn/handle/331005/24794] |
专题 | 中国科学院上海硅酸盐研究所 |
作者单位 | 1.Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Hubei, Peoples R China 2.Wuhan Univ Technol, Sch Sci, Wuhan 430070, Hubei, Peoples R China 3.Wuhan Univ Technol, Ctr Mat Res & Anal, Wuhan 430070, Hubei, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Transparent & Optofunct Adv Inorgan Mat, Shanghai 201800, Peoples R China |
推荐引用方式 GB/T 7714 | Yi, Guoqiang,Li, Weiwei,Song, Jinghong,et al. Structural, spectroscopic and thermal properties of hot-pressed Nd:(Ca0.94Gd0.06)F-2.06 transparent ceramics[J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY,2018,38(9):3240, 3245. |
APA | Yi, Guoqiang,Li, Weiwei,Song, Jinghong,Mei, Bingchu,Zhou, Zhiwei,&Su, Liangbi.(2018).Structural, spectroscopic and thermal properties of hot-pressed Nd:(Ca0.94Gd0.06)F-2.06 transparent ceramics.JOURNAL OF THE EUROPEAN CERAMIC SOCIETY,38(9),3240. |
MLA | Yi, Guoqiang,et al."Structural, spectroscopic and thermal properties of hot-pressed Nd:(Ca0.94Gd0.06)F-2.06 transparent ceramics".JOURNAL OF THE EUROPEAN CERAMIC SOCIETY 38.9(2018):3240. |
入库方式: OAI收割
来源:上海硅酸盐研究所
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