Membrane-assisted propane partial oxidation for solid oxide fuel cell applications
文献类型：期刊论文
| 作者 | He, Zhenyu; Li, Chaoqun; Chen, Chusheng; Tong, Yongcheng1; Luo, Ting1; Zhan, Zhongliang1 |
| 刊名 | JOURNAL OF POWER SOURCES
 |
| 出版日期 | 2018 |
| 卷号 | 392页码:200 |
| 关键词 | Propane Partial oxidation reforming Oxygen-permeable membrane Syngas SOFC |
| ISSN号 | 0378-7753 |
| DOI | 10.1016/j.jpowsour.2018.04.085 |
| 英文摘要 | Conversion of condensable fuels to syngas is required for on-site power generation by solid oxide fuel cells. Here, a membrane reactor is investigated to reform propane into syngas. The reactor consists of two chambers separated by an oxygen-permeable ceramic membrane, and propane is fed into one chamber while air is fed into the other. Propane is reformed into syngas by reacting with the permeated oxygen in the presence of Ru-Ni catalyst. The reactor attains a propane throughput conversion over 90%, H-2, CO yield over 80% and syngas is produced at a rate of 22 mL cm(-2) min(-1) at 850 degrees C. The as-reformed fuel is rich in syngas due to the exclusion of nitrogen in air by the membrane. A disk-shaped solid oxide fuel cell, as fuels with the pre-reformed propane by the membrane reactor, exhibits maximum power densities comparable to the one fueled with pure hydrogen. The fuel cell operates stably with the pre-reformed propane, while it fails rapidly with the un-reformed propane. The membrane reactor shows advantages over the conventional fixed bed reactor in terms of reactor safety and fuel concentration, therefore holding a great promise for use as a pre-reformer in solid oxide fuel cell systems. |
| 学科主题 | Chemistry, Physical ; Electrochemistry ; Energy & Fuels ; Materials Science, Multidisciplinary |
| WOS记录号 | WOS:000435055500023 |
| 出版者 | ELSEVIER SCIENCE BV |
| 资助机构 | This research was supported by National Natural Science Foundation of China (Grant NOs. 51572255, 22176230, 51672298). ; This research was supported by National Natural Science Foundation of China (Grant NOs. 51572255, 22176230, 51672298). |
| 源URL | [http://ir.sic.ac.cn/handle/331005/24812]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 作者单位 | 1.Univ Sci & Technol China, Dept Mat Sci & Engn, Collaborat Innovat Ctr Chem Energy Mat, Lab Mat Energy Convers, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, Zhenyu,Li, Chaoqun,Chen, Chusheng,et al. Membrane-assisted propane partial oxidation for solid oxide fuel cell applications[J]. JOURNAL OF POWER SOURCES,2018,392:200, 205. |
| APA | He, Zhenyu,Li, Chaoqun,Chen, Chusheng,Tong, Yongcheng,Luo, Ting,&Zhan, Zhongliang.(2018).Membrane-assisted propane partial oxidation for solid oxide fuel cell applications.JOURNAL OF POWER SOURCES,392,200. |
| MLA | He, Zhenyu,et al."Membrane-assisted propane partial oxidation for solid oxide fuel cell applications".JOURNAL OF POWER SOURCES 392(2018):200. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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