One-step Synthesis and Enhanced Thermoelectric Properties of Polymer-Quantum Dot Composite Films
文献类型：期刊论文
| 作者 | Shi, Wei1; Qu, Sanyin; Chen, Hongyi1; Chen, Yanling1; Yao, Qin; Chen, Lidong |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2018 |
| 卷号 | 57期号:27页码:8037 |
| ISSN号 | 1433-7851 |
| 关键词 | conducting polymers energy conversion nanocomposites polymerization quantum dots |
| DOI | 10.1002/anie.201802681 |
| 英文摘要 | Conventional syntheses of polymer-inorganic composite thermoelectric materials suffer major problems such as inhomogeneity, large particle size, and oxidation that result in ineffective loading. Now a one-step synthesis can be used to fabricate high-quality small-sized anions codoped poly(3,4-ethylenedioxythiophene):dodecylbenzenesulfonate/Cl-tellurium (PEDOT:DBSA/Cl-Te) composite films using a series of novel Te-IV-based oxidants. The synchronized production of PEDOT and Te results in thick and homogeneous films containing evenly distributed and well-protected Te quantum dots. Owing to the heavily doped crystalline polymer matrix as well as the <5nm unoxidized Te quantum dot loading, at low Te concentrations as 2.1-5.8wt%, the films exhibits high power factors of about 100Wm(-1)K(-2), which is 50% higher compared to a pure PEDOT:DBSA film. |
| 学科主题 | Chemistry, Multidisciplinary |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000436402100016 |
| 资助机构 | This work was supported by the National Natural Science Foundation of China (51632010), National Key Research Program of China (2016YFA0201103), a research grant from the Shanghai government (15JC1400301), International Cooperation Project of Ministry of Science and Technology (2017YFE0107800), the Instrument Developing Project of Chinese Academy of Sciences (ZDKYYQ20180004). ; This work was supported by the National Natural Science Foundation of China (51632010), National Key Research Program of China (2016YFA0201103), a research grant from the Shanghai government (15JC1400301), International Cooperation Project of Ministry of Science and Technology (2017YFE0107800), the Instrument Developing Project of Chinese Academy of Sciences (ZDKYYQ20180004). |
| 源URL | [http://ir.sic.ac.cn/handle/331005/24827]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, 1295 Dingxi Rd, Shanghai 200050, Peoples R China 2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Wei,Qu, Sanyin,Chen, Hongyi,et al. One-step Synthesis and Enhanced Thermoelectric Properties of Polymer-Quantum Dot Composite Films[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(27):8037, 8042. |
| APA | Shi, Wei,Qu, Sanyin,Chen, Hongyi,Chen, Yanling,Yao, Qin,&Chen, Lidong.(2018).One-step Synthesis and Enhanced Thermoelectric Properties of Polymer-Quantum Dot Composite Films.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(27),8037. |
| MLA | Shi, Wei,et al."One-step Synthesis and Enhanced Thermoelectric Properties of Polymer-Quantum Dot Composite Films".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.27(2018):8037. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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