Optimized crystal growth and luminescence properties of Ce3+ ions doped Li6Gd(BO3)(3), Li6Y(BO3)(3) and their mixed crystals
文献类型:期刊论文
作者 | Pan, Shangke3; Zhang, Jianyu; Pan, Jianguo3; Ren, Guohao1; Li, Nan2; Wu, Zhi2; Heng, Yuekun2 |
刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
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出版日期 | 2018 |
卷号 | 751页码:129 |
关键词 | Crystal growth Thermal properties Scintillator Neutron detection |
ISSN号 | 0925-8388 |
DOI | 10.1016/j.jallcom.2018.04.099 |
英文摘要 | Ce3+ ions doped Li6Gd(BO3)(3) crystal is a promising low density scintillators for thermal neutron detection. The Czochralski growth of LGBO crystal have been optimized and single crystals with larger sizes have been grown with different techniques. LGBO crystal bowl with diameter larger than 43 mm were grown with Iridium ring increasing the radial temperature gradient and after-heater decreasing the upside axial temperature gradient. Meanwhile LGBO crystal disk with diameter larger than 50 mm were also grown with very low pulling rate and radial temperature gradient. To investigate the overall performance of LGBO series of crystal, Li6Gd(BO3)(3) crystal and its mixed crystals with Li6Gd(BO3)(3) have also been grown using Czochralski method. The thermal expansion coefficients of LGBO and LYBO crystals were investigated using the high temperature XRD patterns, respectively. The big difference between melting and freezing point meant that the metastable phases have formed during cooling cycle for the Ostwald's rule. The optical transmission spectra, x-ray stimulated, photoluminescence and thermal stimulated luminescence spectra were also investigated, respectively. And Li6Gd0.1Y0.9(BO3)(3):Ce crystal may be the most promising crystals for thermal neutron detection for the best light output by alpha particles and the highest light output ratio alpha/gamma of 0.16. (C) 2018 Elsevier B.V. All rights reserved. |
学科主题 | Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
WOS记录号 | WOS:000432670000017 |
出版者 | ELSEVIER SCIENCE SA |
资助机构 | This work was sponsored by National Natural Science foundation of China (No. 11475242 and 51272263), and K. C. Wong Magna Fund in Ningbo University. ; This work was sponsored by National Natural Science foundation of China (No. 11475242 and 51272263), and K. C. Wong Magna Fund in Ningbo University. |
源URL | [http://ir.sic.ac.cn/handle/331005/24852] ![]() |
专题 | 中国科学院上海硅酸盐研究所 |
作者单位 | 1.Ningbo Univ, Sch Mat Sci & Chem Engn, State Key Lab Base Novel Funct Mat & Preparat Sci, Ningbo 315211, Zhejiang, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 201899, Peoples R China 3.Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China 4.Key Lab Photoelect Mat & Devices Zhejiang Prov, Ningbo 315211, Zhejiang, Peoples R China |
推荐引用方式 GB/T 7714 | Pan, Shangke,Zhang, Jianyu,Pan, Jianguo,et al. Optimized crystal growth and luminescence properties of Ce3+ ions doped Li6Gd(BO3)(3), Li6Y(BO3)(3) and their mixed crystals[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2018,751:129, 137. |
APA | Pan, Shangke.,Zhang, Jianyu.,Pan, Jianguo.,Ren, Guohao.,Li, Nan.,...&Heng, Yuekun.(2018).Optimized crystal growth and luminescence properties of Ce3+ ions doped Li6Gd(BO3)(3), Li6Y(BO3)(3) and their mixed crystals.JOURNAL OF ALLOYS AND COMPOUNDS,751,129. |
MLA | Pan, Shangke,et al."Optimized crystal growth and luminescence properties of Ce3+ ions doped Li6Gd(BO3)(3), Li6Y(BO3)(3) and their mixed crystals".JOURNAL OF ALLOYS AND COMPOUNDS 751(2018):129. |
入库方式: OAI收割
来源:上海硅酸盐研究所
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