Formation of self-limited, stable and conductive interfaces between garnet electrolytes and lithium anodes for reversible lithium cycling in solid-state batteries
文献类型：期刊论文
| 作者 | He, Minghui1; Cui, Zhonghui; Chen, Cheng1; Li, Yiqiu; Guo, Xiangxin2 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2018 |
| 卷号 | 6期号:24页码:11463 |
| ISSN号 | 2050-7488 |
| DOI | 10.1039/c8ta02276c |
| 英文摘要 | Solid-state batteries (SSBs) have already attracted significant attention due to their potential to offer high energy density and excellent safety as compared to the currently used lithium-ion batteries with liquid electrolytes. The use of a lithium anode in SSBs is extremely important to realize these advantages. Starting from the synthesis of a highly conductive cubic garnet solid electrolyte (Li6.375La3Zr1.375Nb0.625O12, LLZNO) using Nb as a structure stabilizer, in this study, we demonstrated the resolution of interfacial problems between the garnet electrolyte and lithium anode and the integration of the lithium anode into garnet-based SSBs by modifying the as-synthesized LLZNO with a Sn thin film. Due to the Sn modification, the interfacial resistances between the garnet electrolyte and the lithium anode decreased approximately 20 times to only 46.6 cm(2). The fast and reversible lithium plating/stripping under high current densities and the excellent battery performance of Li/Sn-LLZNO/LiFePO4 full cells were achieved. This improvement is ascribed to the formation of a Li-Sn alloy interlayer, which severs as a self-limited stable and conductive interface, bridging the garnet electrolyte and the lithium anode and enabling fast and stable lithium transport. As a proof-of-concept, this effective surface modification method will offer inspirations to researchers for overcoming the interfacial problems and promoting the development of high-performance SSBs. |
| 学科主题 | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
| WOS记录号 | WOS:000435829000043 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | The authors would like to thank the National Natural Science Foundation of China (Grant No. 51772314, 51532002, 51771222 and 51702346) and the "Taishan Scholars Program". ; The authors would like to thank the National Natural Science Foundation of China (Grant No. 51772314, 51532002, 51771222 and 51702346) and the "Taishan Scholars Program". |
| 源URL | [http://ir.sic.ac.cn/handle/331005/24853]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Qingdao Univ, Coll Phys, Qingdao 266071, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, Minghui,Cui, Zhonghui,Chen, Cheng,et al. Formation of self-limited, stable and conductive interfaces between garnet electrolytes and lithium anodes for reversible lithium cycling in solid-state batteries[J]. JOURNAL OF MATERIALS CHEMISTRY A,2018,6(24):11463, 11470. |
| APA | He, Minghui,Cui, Zhonghui,Chen, Cheng,Li, Yiqiu,&Guo, Xiangxin.(2018).Formation of self-limited, stable and conductive interfaces between garnet electrolytes and lithium anodes for reversible lithium cycling in solid-state batteries.JOURNAL OF MATERIALS CHEMISTRY A,6(24),11463. |
| MLA | He, Minghui,et al."Formation of self-limited, stable and conductive interfaces between garnet electrolytes and lithium anodes for reversible lithium cycling in solid-state batteries".JOURNAL OF MATERIALS CHEMISTRY A 6.24(2018):11463. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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