Emergence of Uranium as a Distinct Metal Center for Building Intrinsic X-ray Scintillators
文献类型：期刊论文
| 作者 | Wang, Yaxing2; Yin, Xuemiao; Liu, Wei; Xie, Jian; Chen, Junfeng3; Silver, Mark A.; Sheng, Daopeng1; Chen, Lanhua1; Juan Diwu1; Liu, Ning2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2018 |
| 卷号 | 57期号:26页码:7883 |
| 关键词 | metal-organic frameworks photoluminescence uranium X-ray scintillation |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201802865 |
| 英文摘要 | The combination of high atomic number and high oxidation state in U-VI materials gives rise to both high X-ray attenuation efficiency and intense green luminescence originating from ligand-to-metal charge transfer. These two features suggest that U-VI materials might act as superior X-ray scintillators, but this postulate has remained substantially untested. Now the first observation of intense X-ray scintillation in a uranyl-organic framework (SCU-9) that is observable by the naked eye is reported. Combining the advantage in minimizing the non-radiative relaxation during the X-ray excitation process over those of inorganic salts of uranium, SCU-9 exhibits a very efficient X-ray to green light luminescence conversion. The luminescence intensity shows an essentially linear correlation with the received X-ray intensity, and is comparable with that of commercially available CsI:Tl. SCU-9 possesses an improved X-ray attenuation efficiency (E > 20 keV) as well as enhanced radiation resistance and decreased hygroscopy compared to CsI:Tl. |
| 学科主题 | Chemistry, Multidisciplinary |
| WOS记录号 | WOS:000435766800055 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | We are grateful for funding support from the Science Challenge Project (TZ2016004), the National Natural Science Foundation of China (21790370, 21790374, 21761132019), the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD), and the "Young Thousand Talented Program" in China. Support for T.E.A.-S. was provided as part of the Center for Actinide Science and Technology (CAST), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under award number DE-SC0016568. We thank Dr. Guokui Liu for helpful discussion on the emission mechanism. ; We are grateful for funding support from the Science Challenge Project (TZ2016004), the National Natural Science Foundation of China (21790370, 21790374, 21761132019), the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD), and the "Young Thousand Talented Program" in China. Support for T.E.A.-S. was provided as part of the Center for Actinide Science and Technology (CAST), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under award number DE-SC0016568. We thank Dr. Guokui Liu for helpful discussion on the emission mechanism. |
| 源URL | [http://ir.sic.ac.cn/handle/331005/24856]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 作者单位 | 1.Soochow Univ, Jiangsu Higher Educ Inst, Sch Radiol & Interdisciplinary Sci RAD X, State Key Lab Radiat Med & Protect, Suzhou 215123, Peoples R China 2.Soochow Univ, Jiangsu Higher Educ Inst, Collaborat Innovat Ctr Radiat Med, Suzhou 215123, Peoples R China 3.Sichuan Univ, Inst Nucl Sci & Technol, Minist Educ, Key Lab Radiat Phys & Technol, Chengdu 610064, Sichuan, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Transparent Optofunct Inorgan Mat, Shanghai 201899, Peoples R China 5.Albrecht-Schmitt, Thomas E.] Florida State Univ, Dept Chem & Biochem, 95 Chieftain Way, Tallahassee, FL 32306 USA |
| 推荐引用方式 GB/T 7714 | Wang, Yaxing,Yin, Xuemiao,Liu, Wei,et al. Emergence of Uranium as a Distinct Metal Center for Building Intrinsic X-ray Scintillators[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(26):7883, 7887. |
| APA | Wang, Yaxing.,Yin, Xuemiao.,Liu, Wei.,Xie, Jian.,Chen, Junfeng.,...&Wang, Shuao.(2018).Emergence of Uranium as a Distinct Metal Center for Building Intrinsic X-ray Scintillators.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(26),7883. |
| MLA | Wang, Yaxing,et al."Emergence of Uranium as a Distinct Metal Center for Building Intrinsic X-ray Scintillators".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.26(2018):7883. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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