Influence of Electronic Conducting Additives on Cycle Performance of Garnet-based Solid Lithium Batteries
文献类型：期刊论文
| 作者 | Du Fu-Ming; Zhao Ning2; Fang Rui1; Cui Zhong-Hui; Li Yi-Qiu; Guo Xiang-Xin |
| 刊名 | JOURNAL OF INORGANIC MATERIALS
 |
| 出版日期 | 2018 |
| 卷号 | 33期号:4页码:462 |
| 关键词 | solid state lithium batteries interfacial resistance garnet electrolytes lithium anodes composite cathodes |
| ISSN号 | 1000-324X |
| DOI | 10.15541/jim20170167 |
| 英文摘要 | Solid state lithium batteries based on garnet-type solid electrolytes face the problem of contact between the solid electrolytes and the solid cathodes, which deteriorates the cycle performance Aiming to overcome such problem, the solid state batteries with the LiNi1/3Co1/3Mn1/3O2 -based cathodes, the Li6.4La3Zr1.4Ta0.6O12 ceramic electrolytes, and the lithium metal anodes were studied. For constructing the LiNi1/3Co1/3Mn1/3O2 -based composite cathodes, three-kind carbons were used as electronic conducting additives. It is found that the batteries with cathodes containing vapor grown carbon fibers (VGCFs) show better cycle performance than those with granular Ketjen Black as well as Super P carbons. Analysis indicates that the VGCFs result in less side reaction at high charge potential than do other two electronic additives, leading to reduced carbonates that cause the increase of the internal cell resistance. These results suggest that stability of electronic additives has important influence on cycle performance of solid state lithium batteries. |
| 学科主题 | Materials Science, Ceramics |
| WOS记录号 | WOS:000432434500016 |
| 出版者 | SCIENCE PRESS |
| 资助机构 | National Natural Science Foundation of China (51532002, 51402339) ; National Basic Research Program of China (2014CB921004) ; Strategic Priority Research Program of Chinese Academy of Science (XDA09010202) ; Natural Science Foundation of Shanghai (17ZR1434600) ; National Natural Science Foundation of China (51532002, 51402339) ; National Basic Research Program of China (2014CB921004) ; Strategic Priority Research Program of Chinese Academy of Science (XDA09010202) ; Natural Science Foundation of Shanghai (17ZR1434600) |
| 源URL | [http://ir.sic.ac.cn/handle/331005/24982]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Qingdao Univ, Coll Phys, Qingdao 266071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du Fu-Ming,Zhao Ning,Fang Rui,et al. Influence of Electronic Conducting Additives on Cycle Performance of Garnet-based Solid Lithium Batteries[J]. JOURNAL OF INORGANIC MATERIALS,2018,33(4):462, +. |
| APA | Du Fu-Ming,Zhao Ning,Fang Rui,Cui Zhong-Hui,Li Yi-Qiu,&Guo Xiang-Xin.(2018).Influence of Electronic Conducting Additives on Cycle Performance of Garnet-based Solid Lithium Batteries.JOURNAL OF INORGANIC MATERIALS,33(4),462. |
| MLA | Du Fu-Ming,et al."Influence of Electronic Conducting Additives on Cycle Performance of Garnet-based Solid Lithium Batteries".JOURNAL OF INORGANIC MATERIALS 33.4(2018):462. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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