H+ Intercalation into Molybdenum Oxide Nanosheets Under AFM Tip Bias
文献类型：期刊论文
| 作者 | Zou, Jian1; Zeng, Huarong; Wang, Yichao2; Li, Yongxiang |
| 刊名 | PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS
 |
| 出版日期 | 2018 |
| 卷号 | 12期号:4 |
| 关键词 | atomic force microscopy bandgap narrowing MoO3 nanosheets proton intercalation |
| ISSN号 | 1862-6254 |
| DOI | 10.1002/pssr.201700439 |
| 英文摘要 | The local hydrogen ions intercalation behavior in -MoO3 nanoflakes is explored under the electric field of an atomic force microscopy (AFM) tip. Protons are excited by AFM tip bias-induced electrolyzation of absorbed water molecules on the surface of -MoO3 nanosheets in ambient environment, and then intercalated into -MoO3 lattice. The formed HxMoO3 is shown to have a 0.2eV reduction in the bandgap and also altered electric behaviors and surface morphologies. This research provides a unique approach for understanding the relationship between nanoscale hydrogen intercalation and the surface morphology and bandgap of two-dimensional (2D) -MoO3 nanosheets. This investigation of ionic intercalation in 2D-layered materials will help in future nanoscale engineering of batteries, electrochromism, photocatalysis, and supercapacitors. |
| 学科主题 | Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
| WOS记录号 | WOS:000429007400008 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | This work was supported by the National Key R&D Program of China (No. 2016YFA0201103), the National Basic Research Program of China (No. 2015CB654605), and Natural Science Foundation of China (No.51402328, No. 51672293 and No. 61371060). ; This work was supported by the National Key R&D Program of China (No. 2016YFA0201103), the National Basic Research Program of China (No. 2015CB654605), and Natural Science Foundation of China (No.51402328, No. 51672293 and No. 61371060). |
| 源URL | [http://ir.sic.ac.cn/handle/331005/25045]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Inorgan Funct Mat & Devices, Shanghai 200050, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Deakin Univ, Sch Life & Environm Sci, Waurn Ponds, Vic 3216, Australia |
| 推荐引用方式 GB/T 7714 | Zou, Jian,Zeng, Huarong,Wang, Yichao,et al. H+ Intercalation into Molybdenum Oxide Nanosheets Under AFM Tip Bias[J]. PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS,2018,12(4). |
| APA | Zou, Jian,Zeng, Huarong,Wang, Yichao,&Li, Yongxiang.(2018).H+ Intercalation into Molybdenum Oxide Nanosheets Under AFM Tip Bias.PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS,12(4). |
| MLA | Zou, Jian,et al."H+ Intercalation into Molybdenum Oxide Nanosheets Under AFM Tip Bias".PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS 12.4(2018). |
入库方式： OAI收割
来源：上海硅酸盐研究所
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