中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
C-QDs@UiO-66-(COOH)(2) Composite Film via Electrophoretic Deposition for Temperature Sensing

文献类型:期刊论文

作者Feng, Ji-fei; Gao, Shui-ying; Shi, Jianlin5; Liu, Tian-fu; Cao, Rong3,8,11
刊名INORGANIC CHEMISTRY
出版日期2018
卷号57期号:5页码:2447
ISSN号0020-1669
DOI10.1021/acs.inorgchem.7b02595
英文摘要Temperature plays a crucial role in both scientific research and industry. However, traditional temperature sensors, such as liquid-filled thermometers, thermocouples, and transistors, require contact to obtain heat equilibrium between the probe and the samples during the measurement. In addition, traditional temperature sensors have limitations when being used to detect the temperature change of fast-moving samples at smaller scales. Herein, the carbon quantum dots (C-QDs) functionalized metal-organic framework (MOF) composite film, a novel contactless solid optical thermometer, has been prepared via electrophoretic deposition (EPD). Instead of terephthalic acid (H2BDC), 1',2',4',5'-benzenetetracarboxylic (H4BTEC) acid was employed to construct a UiO-66 framework to present two uncoordinated carboxylic groups decorated on the pore surface. The uncoordinated carboxylic groups can generate negative charges, which facilitates the deposition of film on the positive electrode during the EPD process. Moreover, UiO-66-(COOH)(2) MOFs can absorb C-QDs from the solution and prevent C-QDs from aggregating, and the well-dispersed C-QDs impart fluorescence characteristics to composites. As-synthesized composite film was successfully used to detect temperature change in the range of 97-297 K with a relative sensitivity up to 1.3% K-1 at 297 K.
学科主题Chemistry, Inorganic & Nuclear
WOS记录号WOS:000427094000018
出版者AMER CHEMICAL SOC
资助机构This research was supported by the 973 Program (2014CB-845605), NSFC (21331006, 2152010200, 51572260, and 21521061), the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB20000000), and the Key Research Program of Frontier Sciences of the Chinese Academy of Sciences (QYZD-J-SSW-SLH045). ; This research was supported by the 973 Program (2014CB-845605), NSFC (21331006, 2152010200, 51572260, and 21521061), the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB20000000), and the Key Research Program of Frontier Sciences of the Chinese Academy of Sciences (QYZD-J-SSW-SLH045).
源URL[http://ir.sic.ac.cn/handle/331005/25109]  
专题中国科学院上海硅酸盐研究所
作者单位1.[Feng, Ji-fei
2.Gao, Shui-ying
3.Liu, Tian-fu
4.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
5.[Feng, Ji-fei
6.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
7.[Feng, Ji-fei
8.Shi, Jianlin
9.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
10.[Feng, Ji-fei
推荐引用方式
GB/T 7714
Feng, Ji-fei,Gao, Shui-ying,Shi, Jianlin,et al. C-QDs@UiO-66-(COOH)(2) Composite Film via Electrophoretic Deposition for Temperature Sensing[J]. INORGANIC CHEMISTRY,2018,57(5):2447, 2454.
APA Feng, Ji-fei,Gao, Shui-ying,Shi, Jianlin,Liu, Tian-fu,&Cao, Rong.(2018).C-QDs@UiO-66-(COOH)(2) Composite Film via Electrophoretic Deposition for Temperature Sensing.INORGANIC CHEMISTRY,57(5),2447.
MLA Feng, Ji-fei,et al."C-QDs@UiO-66-(COOH)(2) Composite Film via Electrophoretic Deposition for Temperature Sensing".INORGANIC CHEMISTRY 57.5(2018):2447.

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来源:上海硅酸盐研究所

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