Facile fabrication and superior gas sensing properties of spongelike Co-doped ZnO microspheres for ethanol sensors
文献类型:期刊论文
作者 | Xu, Jingjing1; Li, Shengjuan1,2; Li, Lei1; Chen, Leyi1; Zhu, Yufang1,2 |
刊名 | Ceramics International
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出版日期 | 2018 |
卷号 | 44期号:14页码:16773-16780 |
ISSN号 | 02728842 |
DOI | 10.1016/j.ceramint.2018.06.110 |
英文摘要 | In this work, a novel strategy has been adopted for the synthesis of hybrid Co-doped ZnO (Co/ZnO) microspheres using the solvothermal method with a synergistic effect of ultrasonic and microwave radiation. The Co/ZnO microspheres were characterized by XRD, FE-SEM, XPS and BET techniques. Sensing tests revealed that the Co/ZnO microspheres exhibited highly better ethanol sensing properties than pure ZnO nanoparticles did, including lower limit of detection (less than 10 ppm), higher response (ca. 120–100 ppm ethanol), lower operating temperature (ca. 220 °C), faster response (10 s) and recovery time (5 s) and better selectivity. The superior gas sensing properties were mainly attributed to the incorporation of Co, which increased the amount of oxygen vacancies and adsorbed oxygen. The sensing mechanism has been explained by oxygen chemisorption on the ZnO surfaces and subsequent reactions of surface adsorbed oxygen species with the ethanol molecules. © 2018 Elsevier Ltd and Techna Group S.r.l. |
出版者 | Elsevier Ltd |
源URL | [http://ir.sic.ac.cn/handle/331005/25146] ![]() |
专题 | 中国科学院上海硅酸盐研究所 |
作者单位 | 1.School of Materials Science and Engineering, University of Shanghai for Science and Technology, 516 Jungong Road, Shanghai; 200093, China; 2.Shanghai Innovation Institute for Materials, Shanghai; 200444, China |
推荐引用方式 GB/T 7714 | Xu, Jingjing,Li, Shengjuan,Li, Lei,et al. Facile fabrication and superior gas sensing properties of spongelike Co-doped ZnO microspheres for ethanol sensors[J]. Ceramics International,2018,44(14):16773-16780. |
APA | Xu, Jingjing,Li, Shengjuan,Li, Lei,Chen, Leyi,&Zhu, Yufang.(2018).Facile fabrication and superior gas sensing properties of spongelike Co-doped ZnO microspheres for ethanol sensors.Ceramics International,44(14),16773-16780. |
MLA | Xu, Jingjing,et al."Facile fabrication and superior gas sensing properties of spongelike Co-doped ZnO microspheres for ethanol sensors".Ceramics International 44.14(2018):16773-16780. |
入库方式: OAI收割
来源:上海硅酸盐研究所
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