Molecular self-assembly of a nanorod N-Li4Ti5O12/TiO2/C anode for superior lithium ion storage
文献类型：期刊论文
| 作者 | Luo, Sainan1; Zhang, Pengcheng1; Yuan, Tao1,2; Ruan, Jiafeng1; Peng, Chengxin1,2; Pang, Yuepeng1,2; Sun, Hao1,2; Yang, Junhe1,2; Zheng, Shiyou1,2 |
| 刊名 | Journal of Materials Chemistry A
 |
| 出版日期 | 2018 |
| 卷号 | 6期号:32页码:15755-15761 |
| ISSN号 | 20507488 |
| DOI | 10.1039/c8ta05860a |
| 英文摘要 | Spinel lithium titanate (Li4Ti5O12, LTO) is one of the most appealing anode materials for lithium-ion batteries (LIBs) due to its long cycle life and high safety performance. However, its low intrinsic electronic conductivity limits its high rate capability. Herein, we develop a novel one-pot in situ molecular self-assembly approach to prepare a dual N- and anatase-TiO2- modified Li4Ti5O12/C nanorod material (NT-LTO/C). Polypyrrole (PPy), as a pivotal carbon and nitrogen source, is introduced to confine the morphology and particle size of the NT-LTO/C anode. Due to the synergistic effects of the multilevel particle structure, uniform carbon coating, N doping, anatase TiO2 pseudopotential effect and such benefits, the NT-LTO/C electrode delivers a high reversible capacity of 196.3 mA h g-1 at 0.5C, and it maintains 105.5 mA h g-1 even at an ultrahigh rate of 100C with progressive cycling of more than 3000 cycles. In addition, the three electrode pouch full-cell shows much smaller polarization than the pristine one. This novel and facile molecular self-assembly method has broad advanced functional material applications including for ceramics, polymer/carbon-based metal alloys and inorganic non-metallic materials. © 2018 The Royal Society of Chemistry. |
| 出版者 | Royal Society of Chemistry |
| 源URL | [http://ir.sic.ac.cn/handle/331005/25147]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 作者单位 | 1.School of Materials Science and Engineering, University of Shanghai for Science and Technology, Shanghai; 200093, China; 2.Shanghai Innovation Institute for Materials, Shanghai; 200444, China |
| 推荐引用方式 GB/T 7714 | Luo, Sainan,Zhang, Pengcheng,Yuan, Tao,et al. Molecular self-assembly of a nanorod N-Li4Ti5O12/TiO2/C anode for superior lithium ion storage[J]. Journal of Materials Chemistry A,2018,6(32):15755-15761. |
| APA | Luo, Sainan.,Zhang, Pengcheng.,Yuan, Tao.,Ruan, Jiafeng.,Peng, Chengxin.,...&Zheng, Shiyou.(2018).Molecular self-assembly of a nanorod N-Li4Ti5O12/TiO2/C anode for superior lithium ion storage.Journal of Materials Chemistry A,6(32),15755-15761. |
| MLA | Luo, Sainan,et al."Molecular self-assembly of a nanorod N-Li4Ti5O12/TiO2/C anode for superior lithium ion storage".Journal of Materials Chemistry A 6.32(2018):15755-15761. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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