X-ray absorption spectroscopy study of synthetic cobalt blue pigments similar to Kangxi blue and white porcelain
文献类型：期刊论文
| 作者 | Luo, Mi1,4; Zhang, Maolin2; Yan, Wensheng3; Wang, Lihua1; Jiang, Zheng1 |
| 刊名 | Journal of the American Ceramic Society
 |
| 出版日期 | 2018 |
| 卷号 | 101期号:5页码:2130-2136 |
| ISSN号 | 00027820 |
| DOI | 10.1111/jace.15353 |
| 英文摘要 | A series of cobalt blue pigments, which were synthesized based on the chemical compositions of the blue pigments in Kangxi blue and white porcelain, were investigated by Co, Mn, and Fe K-edge and L2,3-edge X-ray absorption spectroscopy to determine the oxidation states and species of the elements and to discern their impact on the blue color. The results reveal that Co is bivalent and mainly located at tetrahedral sites, which is the main parameter controlling the blue color. Mn is mainly present as Mn2+, or CoxZn1-xAl2O4and Fe is mainly present as Fe3+. In particular, Fe3+substitutes the Al in CoAl2O4and occupies octahedral sites with a high Mn content. All the synthetic cobalt blue pigments can form a solid solution with various end-members or an intermediate solution spinel. The spectroscopic determination of the oxidation states and speciation of Co, Mn, and Fe furthers understanding of the coloration of blue pigments in blue and white porcelain. © 2017 The American Ceramic Society |
| 出版者 | Blackwell Publishing Inc. |
| 源URL | [http://ir.sic.ac.cn/handle/331005/25182]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 作者单位 | 1.Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai, China; 2.Institute of Ancient Ceramic, Jingdezhen Ceramic Institute, Jingdezhen, China; 3.National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei; Anhui, China; 4.University of Chinese Academy of Sciences, Beijing, China |
| 推荐引用方式 GB/T 7714 | Luo, Mi,Zhang, Maolin,Yan, Wensheng,et al. X-ray absorption spectroscopy study of synthetic cobalt blue pigments similar to Kangxi blue and white porcelain[J]. Journal of the American Ceramic Society,2018,101(5):2130-2136. |
| APA | Luo, Mi,Zhang, Maolin,Yan, Wensheng,Wang, Lihua,&Jiang, Zheng.(2018).X-ray absorption spectroscopy study of synthetic cobalt blue pigments similar to Kangxi blue and white porcelain.Journal of the American Ceramic Society,101(5),2130-2136. |
| MLA | Luo, Mi,et al."X-ray absorption spectroscopy study of synthetic cobalt blue pigments similar to Kangxi blue and white porcelain".Journal of the American Ceramic Society 101.5(2018):2130-2136. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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