Interphase Engineering Enabled All-Ceramic Lithium Battery
文献类型：期刊论文
| 作者 | Han, Fudong1; Yue, Jie1; Chen, Cheng2; Zhao, Ning2; Fan, Xiulin1; Ma, Zhaohui1; Gao, Tao1; Wang, Fei1; Guo, Xiangxin2; Wang, Chunsheng1 |
| 刊名 | Joule
 |
| 出版日期 | 2018 |
| 卷号 | 2期号:3页码:497-508 |
| DOI | 10.1016/j.joule.2018.02.007 |
| 英文摘要 | Solid-state batteries (SSBs) can essentially improve battery safety. Garnet-type Li7La3Zr2O12(LLZO) is considered one of the most promising solid electrolytes for SSBs. However, the performance of LLZO-based SSBs is limited by the large cathode/electrolyte interfacial resistance. High-rate and long-cycling SSBs were achieved only after adding flammable polymer or liquid electrolyte in the cathode at the sacrifice of safety. Here, we show that an all-ceramic cathode/electrolyte with an extremely low interfacial resistance can be realized by thermally soldering LiCoO2(LCO) and LLZO together with the Li2.3−xC0.7+xB0.3−xO3solid electrolyte interphase through the reaction between the Li2.3C0.7B0.3O3solder and the Li2CO3layers that can be conformally coated on both LLZO and LCO. The all-solid-state Li/LLZO/LCO battery with such an all-ceramic cathode/electrolyte exhibits high cycling stability and high rate performance, constituting a significant step toward the practical applications of SSBs. All-solid-state lithium batteries can essentially improve battery safety. However, the performance of all-solid-state batteries is limited by the large interfacial resistance between electrode and electrolyte. As a compromise, flammable liquid or polymer electrolyte was usually added at the electrode/electrolyte interface at a sacrifice of safety. Here we report a unique strategy of lowering the interfacial resistance between LiCoO2cathode and Li7La3Zr2O12electrolyte, so that all-ceramic cathode composite of intrinsically high safety can be achieved. Such an all-ceramic cathode-electrolyte enabled all-solid-state Li/LLZO/LiCoO2batteries with high cycling stability. In addition, this approach is not limited to LiCoO2cathode but can also be applied to other layered transition-metal oxide cathodes, promoting the practical application of all-solid-state lithium batteries. All-ceramic cathode-electrolyte with a low interfacial resistance can be realized by thermally soldering LiCoO2and Li7La3Zr2O12(LLZO) together with Li2.3−xC0.7+xB0.3−xO3solid electrolyte interphase through the reaction between the Li2.3C0.7B0.3O3solder and the Li2CO3layers that can be spontaneously coated on both LLZO and LiCoO2. The all-solid-state Li/LLZO/LiCoO2battery with such an all-ceramic cathode/electrolyte exhibits high cycling stability and high rate performance. © 2018 Elsevier Inc. |
| 出版者 | Cell Press |
| 源URL | [http://ir.sic.ac.cn/handle/331005/25334]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 作者单位 | 1.Department of Chemical and Biomolecular Engineering, University of Maryland, College Park; MD; 20742, United States; 2.State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai; 200050, China |
| 推荐引用方式 GB/T 7714 | Han, Fudong,Yue, Jie,Chen, Cheng,et al. Interphase Engineering Enabled All-Ceramic Lithium Battery[J]. Joule,2018,2(3):497-508. |
| APA | Han, Fudong.,Yue, Jie.,Chen, Cheng.,Zhao, Ning.,Fan, Xiulin.,...&Wang, Chunsheng.(2018).Interphase Engineering Enabled All-Ceramic Lithium Battery.Joule,2(3),497-508. |
| MLA | Han, Fudong,et al."Interphase Engineering Enabled All-Ceramic Lithium Battery".Joule 2.3(2018):497-508. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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