A Robust and Conductive Black Tin Oxide Nanostructure Makes Efficient Lithium-Ion Batteries Possible
文献类型：期刊论文
| 作者 | Dong, Wujie1; Xu, Jijian2; Wang, Chao1; Lu, Yue3; Liu, Xiangye1; Wang, Xin1; Yuan, Xiaotao1; Wang, Zhe1; Lin, Tianquan2; Sui, Manling3 |
| 刊名 | Advanced Materials
 |
| 出版日期 | 2017 |
| 卷号 | 29期号:24 |
| ISSN号 | 09359648 |
| DOI | 10.1002/adma.201700136 |
| 英文摘要 | SnO2-based lithium-ion batteries have low cost and high energy density, but their capacity fades rapidly during lithiation/delithiation due to phase aggregation and cracking. These problems can be mitigated by using highly conducting black SnO2−x, which homogenizes the redox reactions and stabilizes fine, fracture-resistant Sn precipitates in the Li2O matrix. Such fine Sn precipitates and their ample contact with Li2O proliferate the reversible Sn → LixSn → Sn → SnO2/SnO2−xcycle during charging/discharging. SnO2−xelectrode has a reversible capacity of 1340 mAh g−1and retains 590 mAh g−1after 100 cycles. The addition of highly conductive, well-dispersed reduced graphene oxide further stabilizes and improves its performance, allowing 950 mAh g−1remaining after 100 cycles at 0.2 A g−1with 700 mAh g−1at 2.0 A g−1. Conductivity-directed microstructure development may offer a new approach to form advanced electrodes. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
| 源URL | [http://ir.sic.ac.cn/handle/331005/25369]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 作者单位 | 1.Beijing National Laboratory for Molecular Sciences and State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing; 100871, China; 2.State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai; 200050, China; 3.Institute of Microstructure and Properties of Advanced Materials, Beijing University of Technology, Beijing; 100124, China; 4.Department of Materials Science and Engineering, University of Pennsylvania, Philadelphia; PA; 19104, United States |
| 推荐引用方式 GB/T 7714 | Dong, Wujie,Xu, Jijian,Wang, Chao,et al. A Robust and Conductive Black Tin Oxide Nanostructure Makes Efficient Lithium-Ion Batteries Possible[J]. Advanced Materials,2017,29(24). |
| APA | Dong, Wujie.,Xu, Jijian.,Wang, Chao.,Lu, Yue.,Liu, Xiangye.,...&Huang, Fuqiang.(2017).A Robust and Conductive Black Tin Oxide Nanostructure Makes Efficient Lithium-Ion Batteries Possible.Advanced Materials,29(24). |
| MLA | Dong, Wujie,et al."A Robust and Conductive Black Tin Oxide Nanostructure Makes Efficient Lithium-Ion Batteries Possible".Advanced Materials 29.24(2017). |
入库方式： OAI收割
来源：上海硅酸盐研究所
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