Ion-molecule Interaction in Solutions of Lithium Tetrafluoroborate in Propylene Carbonate: an FTIR Vibrational Spectroscopic Study
文献类型：期刊论文
| 作者 | Zhang, Binbin1,2; Zhou, Yuan1 ; Li, Xiang1; Ren, Xiufeng1; Nian, Hongen1; Shen, Yue1; Yun, Qiang1,2
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| 刊名 | INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
 |
| 出版日期 | 2013-12-01 |
| 卷号 | 8期号:12页码:12735-12740 |
| 关键词 | Ftir Spectroscopy Lithium Tetrafluoroborate Propylene Carbonate (Pc) |
| 文献子类 | Article |
| 英文摘要 | FTIR (Fourier transformed infrared) spectra have been collected and analyzed for solutions of lithium tetrafluoroborate in propylene carbonate (PC). It has been shown that the carbonyl stretch, symmetric ring deformation stretch and ring deformation stretch bands for PC is very sensitive to the interaction between Li+ and the solvent molecule. Their half-peak breadth increases and bands split with the addition of LiBF4, indicating that a strong interaction exists between Li+ and PC molecule mainly through the oxygen group of C=O and ring position of PC. |
| WOS关键词 | NONAQUEOUS ELECTROLYTE-SOLUTIONS ; CATION-SOLVENT INTERACTION ; TRANSPORT-PROPERTIES ; RAMAN INTENSITY ; LOCAL-STRUCTURE ; SOLVATION ; ASSOCIATION ; PERCHLORATE ; BATTERIES ; CONDUCTIVITY |
| WOS研究方向 | Electrochemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000326961400029 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/4444]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源与化学实验室 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Key Lab Salt Lake Resources Chem Qinghai Prov, Xining 810008, Qinghai, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Binbin,Zhou, Yuan,Li, Xiang,et al. Ion-molecule Interaction in Solutions of Lithium Tetrafluoroborate in Propylene Carbonate: an FTIR Vibrational Spectroscopic Study[J]. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,2013,8(12):12735-12740. |
| APA | Zhang, Binbin.,Zhou, Yuan.,Li, Xiang.,Ren, Xiufeng.,Nian, Hongen.,...&Yun, Qiang.(2013).Ion-molecule Interaction in Solutions of Lithium Tetrafluoroborate in Propylene Carbonate: an FTIR Vibrational Spectroscopic Study.INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,8(12),12735-12740. |
| MLA | Zhang, Binbin,et al."Ion-molecule Interaction in Solutions of Lithium Tetrafluoroborate in Propylene Carbonate: an FTIR Vibrational Spectroscopic Study".INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE 8.12(2013):12735-12740. |
入库方式： OAI收割
来源：青海盐湖研究所
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