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Electrochemical performances of a novel high-voltage electrolyte based upon sulfolane and gamma-butyrolactone

文献类型:期刊论文

作者Cui, Xiaoling1; Zhang, Hongming1; Li, Shiyou1; Zhao, Yangyu1; Mao, Liping1; Zhao, Wei1; Li, Yongli1; Ye, Xiushen2
刊名JOURNAL OF POWER SOURCES
出版日期2013-10-15
卷号240页码:476-485
关键词Lithium-ion Battery Lithium Bis(Oxalate)Borate Sulfolane Lini0.5mn1.5o4
文献子类Article
英文摘要To seek the promising candidate for 5 V electrolytes, fluorine-free lithium bis(oxalato)borat (LiBOB) is chosen as the lithium salt, gamma-butyrolactone (GBL) as well as sulfolane (SL) with the property of stability against oxidative decomposition is chosen as supporting electrolyte solvents, and linear diethyl carbonate (DMC) is chosen as the third supporting electrolyte solvent to lower viscosity. After systematical analytical studies, it indicates that SL solvent is the main and key reason for the improvement of electrochemical performance, which not only improves the stability of electrolyte system against oxidative decomposition, but also decreases the electrode polarization resistance. More than that, 1.0 mol L-1 LiBOB-SL/GBL/DMC electrolyte shows good compatibilities with both intercalation hosts as LiNi0.5Mn1.5O4 cathode and carbonaceous anode. It suggests that this novel electrolyte would be an alternative electrolyte for 5 V high-voltage rechargeable lithium-ion batteries based upon LiNi0.5Mn1.5O4 cathode. Crown Copyright (C) 2013 Published by Elsevier B.V. All rights reserved.
WOS关键词LITHIUM-ION BATTERIES ; NANOSIZED LINI0.5MN1.5O4 ; SPINEL CATHODES ; 2 KINDS ; BIS(OXALATE)BORATE ; CELLS ; LIBOB ; FILM ; ADDITIVES ; MIXTURES
WOS研究方向Electrochemistry ; Energy & Fuels
语种英语
WOS记录号WOS:000321803700058
源URL[http://ir.isl.ac.cn/handle/363002/4447]  
专题青海盐湖研究所_青海盐湖研究所知识仓储
青海盐湖研究所_盐湖资源与化学实验室
中国科学院青海盐湖研究所
作者单位1.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
推荐引用方式
GB/T 7714
Cui, Xiaoling,Zhang, Hongming,Li, Shiyou,et al. Electrochemical performances of a novel high-voltage electrolyte based upon sulfolane and gamma-butyrolactone[J]. JOURNAL OF POWER SOURCES,2013,240:476-485.
APA Cui, Xiaoling.,Zhang, Hongming.,Li, Shiyou.,Zhao, Yangyu.,Mao, Liping.,...&Ye, Xiushen.(2013).Electrochemical performances of a novel high-voltage electrolyte based upon sulfolane and gamma-butyrolactone.JOURNAL OF POWER SOURCES,240,476-485.
MLA Cui, Xiaoling,et al."Electrochemical performances of a novel high-voltage electrolyte based upon sulfolane and gamma-butyrolactone".JOURNAL OF POWER SOURCES 240(2013):476-485.

入库方式: OAI收割

来源:青海盐湖研究所

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