中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Growth process of Cu2Al6B4O17 whiskers

文献类型:期刊论文

作者Zhu, Chengcai1,2; Nai, Xueying1; Zhu, Donghai1,2; Guo, Fengqin3; Zhang, Yongxing1,2; Li, Wu1
刊名JOURNAL OF SOLID STATE CHEMISTRY
出版日期2013
卷号197页码:1-6
关键词Crystal Growth Whisker Copper Aluminum Borate
文献子类Article
英文摘要The reactions occurred and growth process in the preparation of copper aluminum borate (Cu2Al6B4O17) whiskers based on flux method (Al-2(SO4)(3)/CuSO4/H3BO3 as raw materials, K2SO4 as flux) were investigated. The thermogravimetric and differential scanning calorimetry analysis (TG-DSC), inductively coupled plasma atomic emission spectrum analysis (ICP-AES) and X-ray diffraction analysis (XRD) results of reactants mixture quenched at various temperatures and phase diagrams of K2SO4-Al-2(SO4)(3) system and B2O3-Al2O3 system showed that the reaction process proceeds through three steps: the formation and decomposition of two different kinds of potassium aluminum sulfate (K3Al(SO4)(3) and KAl(SO4)(2)): the formation of aluminum borate (Al4B2O9) and decomposition of copper sulfate (CuSO4) and boric acid (H3BO3): growth and formation of copper aluminum borate (Cu2Al6B4O17) whiskers. The scanning electron microscopy (SEM) analysis results indicated that morphology in growth of Cu2Al6B4O17 whiskers develops through three stages: nanoparticles, fan-shaped whiskers and agminate-needlelike whiskers. Crown Copyright (c) 2012 Published by Elsevier Inc. All rights reserved.
WOS关键词AL18B4O33 WHISKERS ; BORATE ; NANOWIRES
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000312281000001
源URL[http://ir.isl.ac.cn/handle/363002/4477]  
专题青海盐湖研究所_青海盐湖研究所知识仓储
中国科学院青海盐湖研究所
作者单位1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
3.Qinghai Univ, Dept Basin Educ, Xining 810016, Peoples R China
推荐引用方式
GB/T 7714
Zhu, Chengcai,Nai, Xueying,Zhu, Donghai,et al. Growth process of Cu2Al6B4O17 whiskers[J]. JOURNAL OF SOLID STATE CHEMISTRY,2013,197:1-6.
APA Zhu, Chengcai,Nai, Xueying,Zhu, Donghai,Guo, Fengqin,Zhang, Yongxing,&Li, Wu.(2013).Growth process of Cu2Al6B4O17 whiskers.JOURNAL OF SOLID STATE CHEMISTRY,197,1-6.
MLA Zhu, Chengcai,et al."Growth process of Cu2Al6B4O17 whiskers".JOURNAL OF SOLID STATE CHEMISTRY 197(2013):1-6.

入库方式: OAI收割

来源:青海盐湖研究所

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