Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope, Limitation, and Mechanistic Studies by DFT
文献类型：期刊论文
| 作者 | Li, Lei1; Huang, Genping2; Chen, Zhou2; Liu, Wei1; Wang, Xiufang2; Chen, Yanmei1; Yang, Lijuan1; Li, Wu2; Li, Yahong1,3 |
| 刊名 | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2012-10-01 |
| 期号 | 28页码:5564-5572 |
| 关键词 | Synthetic Methods Hydroamination Gallium Alkynes Reaction Mechanisms Density Functional Calculations |
| 文献子类 | Article |
| 英文摘要 | The successful application of gallium trichloride as a catalyst for the intermolecular hydroamination of alkynes with aromatic amines is reported. The reaction is effective with many aniline derivatives and shows exclusive selectivity for the Markovnikov products. The mechanism of the transformation was investigated by DFT calculations and a plausible pathway is proposed. |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000308939800016 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5570]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215006, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Lei,Huang, Genping,Chen, Zhou,et al. Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope, Limitation, and Mechanistic Studies by DFT[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2012(28):5564-5572. |
| APA | Li, Lei.,Huang, Genping.,Chen, Zhou.,Liu, Wei.,Wang, Xiufang.,...&Li, Yahong.(2012).Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope, Limitation, and Mechanistic Studies by DFT.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(28),5564-5572. |
| MLA | Li, Lei,et al."Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope, Limitation, and Mechanistic Studies by DFT".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .28(2012):5564-5572. |
入库方式： OAI收割
来源：青海盐湖研究所
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