A sulfate-bridged Cu-II complex with 1-D helical-chain structure: Synthesis, structure and magnetic property
文献类型：期刊论文
| 作者 | Yang, Li-Juan1; Lei, Tao2; Liu, Wei1; Chen, Wen-Qian1; Lin, Miao-Shui1; Li, Lei1; Li, Wu2; Li, Yahong1,3 |
| 刊名 | INORGANIC CHEMISTRY COMMUNICATIONS
 |
| 出版日期 | 2012-07-01 |
| 卷号 | 21页码:12-15 |
| 关键词 | Copper(Ii) Complex 1-d Helical Chain Solvothermal Synthesis Magnetic Property |
| 文献子类 | Article |
| 英文摘要 | A new 1-D helical chain complex [Cu(H2L)(SO4)]center dot CH3OH (1) (H2L = N,N-bis(3,5-dimethyl-2-hydroxybenzyl)-N-(2-pyridylmethyl)amine) was synthesized from the reaction of the tripodal tetradentate ligand H2L with CuSO4 center dot 5H(2)O under solvothermal conditions. Complex 1 was fully characterized by X-ray single crystal diffraction, elemental analysis and IR spectroscopy. X-ray analysis revealed that complex 1 displays a 1-D helical chain structure with the two adjacent metals being bridged by a sulfate ion. Each Cu-II ion is penta-coordinated and exhibits a pseudo square pyramidal geometry. The low-temperature magnetic susceptibility measurement for the solid sample of 1 revealed the ferromagnetic Cu-II center dot center dot center dot Cu-II interactions. (C) 2012 Elsevier B.V. All rights reserved. |
| WOS关键词 | COORDINATION CHEMISTRY ; ZIRCONIUM COMPLEXES ; LIGANDS ; AMINE ; POLYMERIZATION ; GENERATION ; CATALYSIS ; CLUSTER |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000306614900004 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5574]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, CAS Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Li-Juan,Lei, Tao,Liu, Wei,et al. A sulfate-bridged Cu-II complex with 1-D helical-chain structure: Synthesis, structure and magnetic property[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2012,21:12-15. |
| APA | Yang, Li-Juan.,Lei, Tao.,Liu, Wei.,Chen, Wen-Qian.,Lin, Miao-Shui.,...&Li, Yahong.(2012).A sulfate-bridged Cu-II complex with 1-D helical-chain structure: Synthesis, structure and magnetic property.INORGANIC CHEMISTRY COMMUNICATIONS,21,12-15. |
| MLA | Yang, Li-Juan,et al."A sulfate-bridged Cu-II complex with 1-D helical-chain structure: Synthesis, structure and magnetic property".INORGANIC CHEMISTRY COMMUNICATIONS 21(2012):12-15. |
入库方式： OAI收割
来源：青海盐湖研究所
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