A unique tetranuclear cubane-like [Ni4O4] complex supported by hydroxyl-rich ligands: Synthesis, crystal structure and magnetic property
文献类型：期刊论文
| 作者 | Zhang, Su-Yun1; Chen, Wen-Qian1; Hu, Bin2; Chen, Yan-Mei1; Li, Wu2; Li, Yahong1,3 |
| 刊名 | INORGANIC CHEMISTRY COMMUNICATIONS
 |
| 出版日期 | 2012-02-01 |
| 卷号 | 16页码:74-77 |
| 关键词 | Tetranuclear Cubane-like Nickel Complex Magnetic Properties |
| 文献子类 | Article |
| 英文摘要 | The tetranuclear cubane-like complex of the formula [Ni-4(HL1)(3)(HL2)(H2O)(CH3OH)] [CH3COO]center dot 2CH(3)OH center dot CH3CN (1) (H(3)L1=3-(2-hydroxybenzylideneamino)propane-1,2-diol; H(2)L2=3-aminoprppane-1,2-diol) has been prepared by a one-pot reaction of nickel(II) acetate, salicylaldehyde and 3-aminopropane-1,2-diol, where the H(3)L1 ligand was generated in situ via the condensation reaction between salicylaldehyde and 3-aminopropane-1,2-diol. The X-ray diffraction analysis of the complex showed a Ni4O4 cubane arrangement and the coordination environments of four Ni(II) ions are different from each other. Magnetic studies indicated ferromagnetic behavior for the complex. The magnetic data were fitted and the parameters were given as g=2.43, J(1)=15.96, and J(2)=4.116. (C) 2011 Elsevier B.V. All rights reserved. |
| WOS关键词 | SINGLE-MOLECULE MAGNETS ; POLYNUCLEAR NICKEL(II) COMPLEXES ; TRANSITION-METAL-COMPLEXES ; GEM-DIOL FORM ; SPIN CLUSTERS ; SCHIFF-BASE ; DI-2-PYRIDYL KETONE ; ACTIVE-SITE ; NI-II ; CHEMISTRY |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000300468800018 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5576]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, CAS Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Su-Yun,Chen, Wen-Qian,Hu, Bin,et al. A unique tetranuclear cubane-like [Ni4O4] complex supported by hydroxyl-rich ligands: Synthesis, crystal structure and magnetic property[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2012,16:74-77. |
| APA | Zhang, Su-Yun,Chen, Wen-Qian,Hu, Bin,Chen, Yan-Mei,Li, Wu,&Li, Yahong.(2012).A unique tetranuclear cubane-like [Ni4O4] complex supported by hydroxyl-rich ligands: Synthesis, crystal structure and magnetic property.INORGANIC CHEMISTRY COMMUNICATIONS,16,74-77. |
| MLA | Zhang, Su-Yun,et al."A unique tetranuclear cubane-like [Ni4O4] complex supported by hydroxyl-rich ligands: Synthesis, crystal structure and magnetic property".INORGANIC CHEMISTRY COMMUNICATIONS 16(2012):74-77. |
入库方式： OAI收割
来源：青海盐湖研究所
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