Magnesium complexes supported by pyrrolyl ligands: syntheses, characterizations, and catalytic activities towards the polymerization of epsilon-caprolactone
文献类型：期刊论文
| 作者 | Lin, Miaoshui1; Liu, Wei1; Chen, Zhou2; Yang, Lijuan1; Pei, Hao1; Wu, Jian1; Wan, Xiaoyu1; Lei, Tao2; Li, Yahong1,3 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2012 |
| 卷号 | 2期号:8页码:3451-3457 |
| 文献子类 | Article |
| 英文摘要 | The syntheses, structures and catalytic activities of five magnesium complexes supported by HL1 (HL1 = N-(1H-pyrrol-2-ylmethylene)(2-pyridinyl)methanimine), HL2 (HL2 = N-(1H-pyrrol-2-ylmethylene)-2-pyridineethanimine), HL3 (HL3 = 2-pyrrolecarbaldmethylimine), HL4 (HL4 = N-((1H-pyrrol-2-yl)methylene)(phenyl)methanimine) and HL5 (HL5 = N-((1H-pyrrol-2-yl)methylene)-2-phenylethanimine) are described. Treatment of (MgBu2)-Bu-n with 2 equiv. of HL1, HL2, HL3, HL4 and HL5, respectively, results in the formation of Mg(L1)(2) (1), Mg(L2)(2) (2), Mg(L3)(2)(THF)(2) (3), Mg(L4)(2)(THF)(2) (4) and Mg(L5)(2)(THF)(2) (5). All complexes have been characterized by elemental analyses and NMR studies. The solid-state structures of complexes 2, 3, and 4 have been further established by single X-ray crystallography. All complexes were found to be active catalysts for the ring-opening polymerization of epsilon-caprolactone. |
| WOS关键词 | RING-OPENING POLYMERIZATION ; COORDINATION CHEMISTRY ; GRIGNARD-REAGENTS ; ZINC-COMPLEXES ; CYCLIC ESTERS ; HYDROAMINATION ; LACTIDE ; AMINOALKENES ; ALKOXIDES ; ALKYL |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000302023500053 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5582]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215006, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, CAS Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lin, Miaoshui,Liu, Wei,Chen, Zhou,et al. Magnesium complexes supported by pyrrolyl ligands: syntheses, characterizations, and catalytic activities towards the polymerization of epsilon-caprolactone[J]. RSC ADVANCES,2012,2(8):3451-3457. |
| APA | Lin, Miaoshui.,Liu, Wei.,Chen, Zhou.,Yang, Lijuan.,Pei, Hao.,...&Li, Yahong.(2012).Magnesium complexes supported by pyrrolyl ligands: syntheses, characterizations, and catalytic activities towards the polymerization of epsilon-caprolactone.RSC ADVANCES,2(8),3451-3457. |
| MLA | Lin, Miaoshui,et al."Magnesium complexes supported by pyrrolyl ligands: syntheses, characterizations, and catalytic activities towards the polymerization of epsilon-caprolactone".RSC ADVANCES 2.8(2012):3451-3457. |
入库方式： OAI收割
来源：青海盐湖研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。