Synthesis, characterization, and thermal decomposition of oxamido heterobinuclear Cu(II)-Ln(III) complexes
文献类型：期刊论文
| 作者 | Wang, HD; Chen, Y; Li, YT; Zeng, XC |
| 刊名 | THERMOCHIMICA ACTA
 |
| 出版日期 | 2004-03-23 |
| 卷号 | 412期号:1-2页码:97-105 |
| 关键词 | Cu(Ii)-ln(Iii) Heterobinuclear Complex Thermal Decomposition Non-isothermal Kinetic |
| 文献子类 | Article |
| 英文摘要 | Three oxamido-bridged copper(II)-lanthanide(III) heterobinuclear complexes described by the overall formula Cu(oxen)Ln(phen)(2)(ClO4)(3) (oxen = N,N'-bis(2-aminoethyl)oxamide, Ln = Eu, Gd, and Er, phen = 1,10-phenanthroline), have been synthesized and characterized by the elemental analyses, IR spectroscopy, X-ray analysis and energy dispersive spectrometer (EDS) analysis. The thermal decomposition of the complexes was studied by TG, DTG, and DTA technique under dynamic nitrogen atmosphere. The decompositions of these complexes took place through four stages. The second and third stages were analyzed kinetically by means of the Achar method and the Coats-Redfern method. The activation energies, pre-exponential factors and the most probable kinetic model function were determined for these stages. (C) 2003 Elsevier B.V. All rights reserved. |
| WOS关键词 | COPPER(II)-LANTHANIDE(III) COMPLEXES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000220132200012 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5602]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Sichuan Univ, Sichuan Key Lab Green Chem & Technol, Fac Chem, Chengdu 610064, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China 3.Logist Engn Univ, Dept Appl Oil Engn, Chongqing 400016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, HD,Chen, Y,Li, YT,et al. Synthesis, characterization, and thermal decomposition of oxamido heterobinuclear Cu(II)-Ln(III) complexes[J]. THERMOCHIMICA ACTA,2004,412(1-2):97-105. |
| APA | Wang, HD,Chen, Y,Li, YT,&Zeng, XC.(2004).Synthesis, characterization, and thermal decomposition of oxamido heterobinuclear Cu(II)-Ln(III) complexes.THERMOCHIMICA ACTA,412(1-2),97-105. |
| MLA | Wang, HD,et al."Synthesis, characterization, and thermal decomposition of oxamido heterobinuclear Cu(II)-Ln(III) complexes".THERMOCHIMICA ACTA 412.1-2(2004):97-105. |
入库方式： OAI收割
来源：青海盐湖研究所
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