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Raman spectroscopic analysis of supersaturated aqueous solution of MgO-B2O3-32%MgCl2-H2O during acidification and dilution
文献类型：期刊论文
| 作者 | Liu, ZH; Gao, B; Li, SN; Hu, MC; Xia, SP |
| 刊名 | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
 |
| 出版日期 | 2004-11-01 |
| 卷号 | 60期号:13页码:3125-3128 |
| 关键词 | Raman Spectra Borate Aqueous Solution Acidification Dilution |
| 文献子类 | Article |
| 英文摘要 | Raman spectra of supersaturated aqueous solution of MgO.B2O3-32%MgCl2-H2O during acidification/alkalization and dilution have been studied. The assignments of the recorded Raman shift are given. The main existing forms of polyborate anions and their interaction in borate aqueous solution have been proposed through spectroscopic analysis. The experimental results indicate that the higher concentration of cation are beneficial not only to the dissolution of boric acid but also to the polymerization of polyborate anions. The existing forms and interaction among them also depend on the concentration of boron and the pH value in solution. (C) 2004 Elsevier B.V. All rights reserved. |
| WOS研究方向 | Spectroscopy |
| 语种 | 英语 |
| WOS记录号 | WOS:000224847900026 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5613]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Peoples R China 2.Acad Sinica, Xian Branch, Inst Salt Lakes, Xian 710043, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, ZH,Gao, B,Li, SN,et al. Raman spectroscopic analysis of supersaturated aqueous solution of MgO-B2O3-32%MgCl2-H2O during acidification and dilution[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2004,60(13):3125-3128. |
| APA | Liu, ZH,Gao, B,Li, SN,Hu, MC,&Xia, SP.(2004).Raman spectroscopic analysis of supersaturated aqueous solution of MgO-B2O3-32%MgCl2-H2O during acidification and dilution.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,60(13),3125-3128. |
| MLA | Liu, ZH,et al."Raman spectroscopic analysis of supersaturated aqueous solution of MgO-B2O3-32%MgCl2-H2O during acidification and dilution".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 60.13(2004):3125-3128. |
入库方式： OAI收割
来源：青海盐湖研究所
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