A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear copper complex incorporating a hydroxyl-rich ligand: syntheses and crystal structures
文献类型：期刊论文
| 作者 | Zhang, Suyun1; Chen, Wenqian1; Hu, Bin2 ; Chen, Yanmei1; Zheng, Lina1; Li, Yahong1,3; Li, Wu2
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| 刊名 | JOURNAL OF COORDINATION CHEMISTRY
 |
| 出版日期 | 2012 |
| 卷号 | 65期号:23页码:4147-4155 |
| 关键词 | Tetranuclear Cubane-like Nickel Copper |
| 文献子类 | Article |
| 英文摘要 | A tetranuclear cubane-like cluster [Ni-4(HL)(4)(DMSO)(2)] center dot 2DMSO center dot H2O (1) and a dinuclear compound [Cu2Cl2(H2L)(2)] center dot 1.5MeOH (2) (H3L = 3-(2-hydroxy-benzylideneamino)propane-1,2-diol) have been prepared and characterized by X-ray single crystal diffraction, IR, and elemental analysis. The X-ray diffraction analysis indicated that the four metals of 1 showed a Ni4O4 cubane arrangement, and two of the six faces of the Ni4O4 cubane were capped by DMSO. Complex 1 is the first reported DMSO capped Ni4O4 cubane cluster. Complex 2 contains a u(2)-Cl bridged dinuclear core with each Cu-II ion exhibiting pseudo square pyramidal geometry. |
| WOS关键词 | SINGLE-CHAIN MAGNETS ; SPIN CLUSTERS ; NI-II ; POLYNUCLEAR ; GENERATION ; BEHAVIOR ; FAMILY ; ANION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000310309500009 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5643]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源与化学实验室 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 73000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Suyun,Chen, Wenqian,Hu, Bin,et al. A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear copper complex incorporating a hydroxyl-rich ligand: syntheses and crystal structures[J]. JOURNAL OF COORDINATION CHEMISTRY,2012,65(23):4147-4155. |
| APA | Zhang, Suyun.,Chen, Wenqian.,Hu, Bin.,Chen, Yanmei.,Zheng, Lina.,...&Li, Wu.(2012).A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear copper complex incorporating a hydroxyl-rich ligand: syntheses and crystal structures.JOURNAL OF COORDINATION CHEMISTRY,65(23),4147-4155. |
| MLA | Zhang, Suyun,et al."A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear copper complex incorporating a hydroxyl-rich ligand: syntheses and crystal structures".JOURNAL OF COORDINATION CHEMISTRY 65.23(2012):4147-4155. |
入库方式： OAI收割
来源：青海盐湖研究所
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