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Isopiestic Measurement and Solubility Evaluation of the Ternary System LiCl-SrCl2-H2O at 298.15 K
文献类型:期刊论文
作者 | Guo, Lijiang1; Sun, Bai1; Zeng, Dewen1,2; Yao, Yan1; Han, Haijun1 |
刊名 | JOURNAL OF CHEMICAL AND ENGINEERING DATA
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出版日期 | 2012-03-01 |
卷号 | 57期号:3页码:817-827 |
文献子类 | Article |
英文摘要 | Water activity in the ternary system LiCl-SrCl2-H2O and its sub-binary systems has been elaborately measured by the isopiestic method. The measured water activities were used to justify the reliability of solubility isotherms reported in literature by correlating them with two thermodynamic models, that is, the extended Pitzer model and the Pitzer-Simonson-Clegg model. It was found that the extended Pitzer model cannot correlate consistently the water activities measured and either set of the solubility isotherms reported in literature for this concerned system, no matter how its parameters were adjusted. However, the Pitzer-Simonson-Clegg model can correlate consistently our measured water activities and the solubility isotherms reported by the literature (Kydynov et al. Issled. Obl. Khim. Tekhnol. Miner. Solei Okislov 1965, 146-150), which should be more reliable than solubility data reported in other references. |
WOS关键词 | ION-INTERACTION MODEL ; ACTIVITY-COEFFICIENTS ; OSMOTIC COEFFICIENTS ; STRONTIUM CHLORIDE ; AQUEOUS-SOLUTIONS ; THERMODYNAMICS ; 25-DEGREES-C ; MIXTURES ; MULTICOMPONENT ; REPRESENTATION |
WOS研究方向 | Chemistry ; Engineering |
语种 | 英语 |
WOS记录号 | WOS:000301169900021 |
源URL | [http://ir.isl.ac.cn/handle/363002/5647] ![]() |
专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
作者单位 | 1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China 2.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China |
推荐引用方式 GB/T 7714 | Guo, Lijiang,Sun, Bai,Zeng, Dewen,et al. Isopiestic Measurement and Solubility Evaluation of the Ternary System LiCl-SrCl2-H2O at 298.15 K[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2012,57(3):817-827. |
APA | Guo, Lijiang,Sun, Bai,Zeng, Dewen,Yao, Yan,&Han, Haijun.(2012).Isopiestic Measurement and Solubility Evaluation of the Ternary System LiCl-SrCl2-H2O at 298.15 K.JOURNAL OF CHEMICAL AND ENGINEERING DATA,57(3),817-827. |
MLA | Guo, Lijiang,et al."Isopiestic Measurement and Solubility Evaluation of the Ternary System LiCl-SrCl2-H2O at 298.15 K".JOURNAL OF CHEMICAL AND ENGINEERING DATA 57.3(2012):817-827. |
入库方式: OAI收割
来源:青海盐湖研究所
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