Zn-II, Ni-II, and Mn-II Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses, Structures, and Luminescent and Magnetic Properties
文献类型：期刊论文
| 作者 | Liu Yong-Lu1; Chen Yan-Mei1,2; Gao Qian1; Liu Wei1; Li Ya-Hong1,3; Li Wu2 |
| 刊名 | CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
 |
| 出版日期 | 2014 |
| 卷号 | 33期号:8页码:1171-1183 |
| 关键词 | Solvothermal N-hydroxy-pyridine-2-carboxamidine Luminescence Magnetic Property |
| 文献子类 | Article |
| 英文摘要 | The employment of N-hydroxy-pyridine-2-carboxamidine in the coordination chemistry of zinc(II), nickel(II) and manganese(II) under solvothermal conditions is reported. Four complexes of compositions, [Zn-2(O2CMe)(3){(py)C(NH2)NOH}(4)](OH) (1), [Zn-4(OH)(2){(py)C(NH2)-NO}(4)Cl-2]center dot 3MeCN (2), [Ni(SO4)(H2O) {(py)C(NH2)NOH}(2)]center dot H2O (3) and [Mn(SO4) {(py)C(NH2)-NOH}(2)](n) (4), have been synthesized by rationally choosing different metal salts and dexterously employing acetate and sulfate ions as the bridging groups. Luminescent properties for 2 suggested strong emission in the solid state at room temperature. Variable temperature (2.0 similar to 300 K) magnetic studies for the linear chain complex 4 indicate weak antiferromagnetic Mn(II)center dot center dot center dot Mn(II) exchange interactions. |
| WOS关键词 | 3D-METAL CLUSTER CHEMISTRY ; COORDINATION CHEMISTRY ; CYCLIC POLYETHERS ; CRYSTAL-STRUCTURE ; SALT COMPLEXES ; METAL-SALTS ; LIGANDS ; SPIN ; PYRIDINE-2-AMIDOXIME ; HEXANUCLEAR |
| WOS研究方向 | Chemistry ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000341071000011 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5671]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu Yong-Lu,Chen Yan-Mei,Gao Qian,et al. Zn-II, Ni-II, and Mn-II Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses, Structures, and Luminescent and Magnetic Properties[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2014,33(8):1171-1183. |
| APA | Liu Yong-Lu,Chen Yan-Mei,Gao Qian,Liu Wei,Li Ya-Hong,&Li Wu.(2014).Zn-II, Ni-II, and Mn-II Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses, Structures, and Luminescent and Magnetic Properties.CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,33(8),1171-1183. |
| MLA | Liu Yong-Lu,et al."Zn-II, Ni-II, and Mn-II Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses, Structures, and Luminescent and Magnetic Properties".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 33.8(2014):1171-1183. |
入库方式： OAI收割
来源：青海盐湖研究所
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