Physical-chemical properties of nickel analogs ionic liquid based on choline chloride
文献类型：期刊论文
| 作者 | Wang, Huaiyou1,2 ; Jia, Yongzhong1; Wang, Xiaohua1; Yao, Ying1; Jing, Yan1
|
| 刊名 | JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
 |
| 出版日期 | 2014-02-01 |
| 卷号 | 115期号:2页码:1779-1785 |
| 关键词 | Analogs Ionic Liquid Structure Analysis Viscosity Conductivity Density Thermal Stability |
| 文献子类 | Article |
| 英文摘要 | In this paper, a homogeneous, green analogs ionic liquid containing choline chloride and nickel chloride hexahydrate is formed. The structure of the analogs ionic liquid is preliminary investigated by Fourier transform infrared spectroscopy. It is shown that the nickel chloride hexahydrate bond via hydrogen bonds with choline chloride and urea. The physico-chemical properties of the analogs ionic liquid such as viscosity, conductivity, density, and thermal stability are measured as a function of temperature and composition. The thermal expansion coefficients (r), the molar Gibbs energy of activation (Delta G*) for viscous flow, the molar enthalpy of activation (Delta H*), and the molar entropy of activation (Delta S*) for viscous flow have been calculated. A straight-line equation is used to fit the density data while the Arrhenius equation is used to fit both viscosity and conductivity. Thermal stability of analogs ionic liquid was carried out from room temperature to 973.15 K. It indicates that analogs ionic liquid is stable from room temperature to 488.2 K. |
| WOS关键词 | DEEP EUTECTIC SOLVENTS ; PHYSICOCHEMICAL PROPERTIES ; MAGNESIUM-CHLORIDE ; ELECTRODEPOSITION ; MIXTURES ; UREA ; TEMPERATURE ; SALTS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000330729100088 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5680]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源综合利用工程技术中心 青海盐湖研究所_盐湖资源与化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Huaiyou,Jia, Yongzhong,Wang, Xiaohua,et al. Physical-chemical properties of nickel analogs ionic liquid based on choline chloride[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2014,115(2):1779-1785. |
| APA | Wang, Huaiyou,Jia, Yongzhong,Wang, Xiaohua,Yao, Ying,&Jing, Yan.(2014).Physical-chemical properties of nickel analogs ionic liquid based on choline chloride.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,115(2),1779-1785. |
| MLA | Wang, Huaiyou,et al."Physical-chemical properties of nickel analogs ionic liquid based on choline chloride".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 115.2(2014):1779-1785. |
入库方式： OAI收割
来源：青海盐湖研究所
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