中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Boron isotopic fractionation and trace element incorporation in various species of modern corals in Sanya Bay, South China Sea

文献类型:期刊论文

作者Wei, Haizhen1; Jiang, Shaoyong1,2; Xiao, Yingkai3; Hemming, N. Gary4,5
刊名JOURNAL OF EARTH SCIENCE
出版日期2014-06-01
卷号25期号:3页码:431-444
关键词Boron Isotope Paleo-ph Proxy Boron Isotopic Fractionation Trace Element Modern Coral
文献子类Article
英文摘要The boron isotope paleo-pH proxy has been extensively studied due to its potential for understanding past climate change, and further calibrations were considered for accurate applications of the proxy because of significant variability related to biocarbonate microstructure. In this work, we studied the boron isotopic fractionation between modern marine corals and their coexisting seawater collected along shallow area in Sanya Bay, South China Sea. The apparent partition coefficient of boron (K-D) ranged from 0.83x10(-3) to 1.69x10(-3), which are in good agreement with previous studies. As the analyzed coral skeleton (similar to 5 g) spanned the growth time period of 1-2 years, we discussed the boron isotopic fractionation between pristine corals and modern seawater using the annual mean seawater pH of 8.12 in this sea area. Without taking the vital effect into account, (B-11/B-10)(coral) values of all living corals spread over the curves of (B-11/B-10)(borate) vs. (B-11/B-10)(sw) with the alpha (4-3) values ranging from 0.974 to 0.982. After calibrating the biological effect on the calcifying fluid pH, the field-based calcification on calcifying fluid pH (i.e., Delta(pH(biol)-pH(sw))) for coral species of Acropora, Pavona, Pocillopora, Faviidae, and others including Proites are 0.42, 0.33, 0.36, 0.19, respectively, and it is necessary to be validated by coral culturing experiment in the future. Correlations in B/Ca vs. Sr/Ca and B/Ca vs. pH(biol) approve temperature and calcifying fluid pH influence on skeletal B/Ca. Fundamental understanding of the thermodynamic basis of the boron isotopes in marine carbonates and seawater will strengthen the confidence in the use of paleo-pH proxy as a powerful tool to monitor atmospheric CO2 variations in the past.
WOS关键词PARTITION-FUNCTION RATIOS ; MOLECULAR-ORBITAL CALCULATIONS ; BENTHIC FORAMINIFERAL B/CA ; PAST OCEAN PH ; ION-EXCHANGE ; SEAWATER PH ; CALCITE PRECIPITATION ; CARBONATE ION ; BORIC ACIDS ; TEMPERATURE
WOS研究方向Geology
语种英语
WOS记录号WOS:000338228900002
源URL[http://ir.isl.ac.cn/handle/363002/5705]  
专题青海盐湖研究所_青海盐湖研究所知识仓储
中国科学院青海盐湖研究所
作者单位1.Nanjing Univ, Dept Earth Sci, State Key Lab Mineral Deposits Res, Nanjing 210093, Jiangsu, Peoples R China
2.China Univ Geosci, Fac Earth Resources, State Key Lab Geol Proc & Mineral Resources, Wuhan 430074, Peoples R China
3.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810003, Peoples R China
4.Columbia Univ, Lamont Doherty Earth Observ, Palisades, NY 10964 USA
5.CUNY Queens Coll, Sch Earth & Environm Sci, Flushing, NY 11367 USA
推荐引用方式
GB/T 7714
Wei, Haizhen,Jiang, Shaoyong,Xiao, Yingkai,et al. Boron isotopic fractionation and trace element incorporation in various species of modern corals in Sanya Bay, South China Sea[J]. JOURNAL OF EARTH SCIENCE,2014,25(3):431-444.
APA Wei, Haizhen,Jiang, Shaoyong,Xiao, Yingkai,&Hemming, N. Gary.(2014).Boron isotopic fractionation and trace element incorporation in various species of modern corals in Sanya Bay, South China Sea.JOURNAL OF EARTH SCIENCE,25(3),431-444.
MLA Wei, Haizhen,et al."Boron isotopic fractionation and trace element incorporation in various species of modern corals in Sanya Bay, South China Sea".JOURNAL OF EARTH SCIENCE 25.3(2014):431-444.

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来源:青海盐湖研究所

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