A series of Zn-II and Co-II complexes based on 2-(imidazo[1,5-a]pyridin-3-yl)phenol: syntheses, structures, and luminescent and magnetic properties
文献类型：期刊论文
| 作者 | Gao, Qian1; Chen, Yanmei1,2; Liu, Yonglu1; Li, Cong1; Gao, Dandan2 ; Wu, Bing1; Li, Haiyan1; Li, Yahong1,3; Liu, Wei1; Li, Wu2
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| 刊名 | JOURNAL OF COORDINATION CHEMISTRY
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| 出版日期 | 2014 |
| 卷号 | 67期号:10页码:1673-1692 |
| 关键词 | Crystal Structures Dft And tdDft Calculations 2-(Imidazo[1 Luminescent Properties 5-a]Pyridin-3-yl)Phenol Magnetic Properties |
| 文献子类 | Article |
| 英文摘要 | The employment of 2-(imidazo[1,5-a]pyridin-3-yl)phenol (HIPP) in Zn-II and Co-II coordination chemistry is reported. A series of complexes of compositions, [Zn(HIPP)(2)Cl-2] (1), [Zn-2(IPP)(4)] (2), [Co-2(HIPP)(4)(SO4)(2)] (3), [Co-3(IPP)(6)] (4), and [Co-2(IPP)(2)(CH3COO)(2)](n) (5), have been synthesized via choosing appropriate metal salts and different solvents. Complexes of various nuclearities are obtained from mono-, di-, trinuclear complexes to 1-D chain polymer. UV-vis absorption properties have been investigated and rationalized by density functional theory and time-dependent DFT calculations. In addition, luminescence studies suggested strong emissions for 1, 2, and 3 in the solid state at room temperature. Variable temperature (2.0-300 K) magnetic studies for 3, 4, and 5 indicate weak antiferromagnetic coupling between the metal centers in 3 and 5, and weak ferromagnetic Co-II center dot center dot center dot Co-II exchange interactions in 4. |
| WOS关键词 | NITROGENOUS HETEROCYCLIC LIGAND ; MEDIATED CONTROLLABLE CREATION ; QUATERNARY CARBON CENTERS ; METAL-ORGANIC FRAMEWORKS ; COORDINATION POLYMERS ; CRYSTAL-STRUCTURES ; COBALT(II) COMPLEXES ; COPPER-COMPLEXES ; ZINC(II) ; DENSITY |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000340149800001 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5711]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源综合利用工程技术中心 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Suzhou, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Qian,Chen, Yanmei,Liu, Yonglu,et al. A series of Zn-II and Co-II complexes based on 2-(imidazo[1,5-a]pyridin-3-yl)phenol: syntheses, structures, and luminescent and magnetic properties[J]. JOURNAL OF COORDINATION CHEMISTRY,2014,67(10):1673-1692. |
| APA | Gao, Qian.,Chen, Yanmei.,Liu, Yonglu.,Li, Cong.,Gao, Dandan.,...&Li, Wu.(2014).A series of Zn-II and Co-II complexes based on 2-(imidazo[1,5-a]pyridin-3-yl)phenol: syntheses, structures, and luminescent and magnetic properties.JOURNAL OF COORDINATION CHEMISTRY,67(10),1673-1692. |
| MLA | Gao, Qian,et al."A series of Zn-II and Co-II complexes based on 2-(imidazo[1,5-a]pyridin-3-yl)phenol: syntheses, structures, and luminescent and magnetic properties".JOURNAL OF COORDINATION CHEMISTRY 67.10(2014):1673-1692. |
入库方式： OAI收割
来源：青海盐湖研究所
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