FTIR spectroscopic studies of lithium tetrafluoroborate in propylene carbonate plus diethyl carbonate mixtures
文献类型：期刊论文
| 作者 | Zhang, Binbin1,2; Zhou, Yuan1 ; Li, Xiang1,2; Ren, Xiufeng1,2; Nian, Hongen1,2; Shen, Yue1; Yun, Qiang1,2
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| 刊名 | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
 |
| 出版日期 | 2014-03-25 |
| 卷号 | 122页码:59-64 |
| 关键词 | Ftir Spectroscopy Lithium Tetrafluoroborate Propylene Carbonate (Pc) Diethyl Carbonate (Dec) |
| 文献子类 | Article |
| 英文摘要 | FTIR (Fourier transformed infrared) spectra have been collected and analyzed for solutions of lithium tetrafluoroborate in propylene carbonate (PC), diethyl carbonate (DEC), and PC + DEC mixtures. It has been shown that the carbonyl stretch bands of PC and DEC, the ring of PC and the ether oxygen stretch bands of DEC are all very sensitive to the interaction between Li+ and the solvent molecules. New shoulders appear and the original bands split with the addition of LiBF4, indicating that a strong interaction between Li+ and molecules of PC and DEC exists through the oxygen group of C=O and ring of PC and both C=O oxygen and ether oxygen atoms of DEC. In addition, no preferential solvation of Li+ in LiBF4/PC + DEC solutions was detected. (C) 2013 Elsevier B.V. All rights reserved. |
| WOS关键词 | NONAQUEOUS ELECTROLYTE-SOLUTIONS ; CATION-SOLVENT INTERACTION ; ION SOLVATION ; ETHYLENE CARBONATE ; 4-METHOXYMETHYL-ETHYLENE CARBONATE ; PREFERENTIAL SOLVATION ; TRANSPORT-PROPERTIES ; RAMAN INTENSITY ; LOCAL-STRUCTURE ; MIXED-SOLVENTS |
| WOS研究方向 | Spectroscopy |
| 语种 | 英语 |
| WOS记录号 | WOS:000332438300007 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5720]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源与化学实验室 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Salt Lake Resources & Chem, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources Chem Qinghai Prov, Xining 810008, Qinghai, Peoples R China 2.Univ Chinese Acad Sci, Being 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Binbin,Zhou, Yuan,Li, Xiang,et al. FTIR spectroscopic studies of lithium tetrafluoroborate in propylene carbonate plus diethyl carbonate mixtures[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2014,122:59-64. |
| APA | Zhang, Binbin.,Zhou, Yuan.,Li, Xiang.,Ren, Xiufeng.,Nian, Hongen.,...&Yun, Qiang.(2014).FTIR spectroscopic studies of lithium tetrafluoroborate in propylene carbonate plus diethyl carbonate mixtures.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,122,59-64. |
| MLA | Zhang, Binbin,et al."FTIR spectroscopic studies of lithium tetrafluoroborate in propylene carbonate plus diethyl carbonate mixtures".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 122(2014):59-64. |
入库方式： OAI收割
来源：青海盐湖研究所
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