Synthesis, structures and properties of the first series of Sr-II-M-II (M = Cu, Co, Ni and Zn) coordination polymers based on pyridine-2,5-dicarboxylic acid
文献类型：期刊论文
| 作者 | Chen, Yanmei1; She, Shixiong1; Gao, Qian1; Gao, Dandan2; Wang, Derong2; Li, Yahong1,3; Liu, Wei1; Li, Wu2 |
| 刊名 | CRYSTENGCOMM
 |
| 出版日期 | 2014 |
| 卷号 | 16期号:6页码:1091-1102 |
| 文献子类 | Article |
| 英文摘要 | The first series of heterometallic Sr-II-M-II (M = Cu, Co, Ni and Zn) coordination polymers based on pyridine-2,5-dicarboxylic acid (H(2)pydc) are reported. Eight complexes of compositions, [Sr(pydc)(H2O)](n) (1), [CuSr(pydc)(2)(H2O)(4)](n) (2), [CoSr(pydc)(2)(H2O)(6)](2n)center dot H2O (3), [NiSr(pydc)(2)(H2O)(4)](n)center dot 3nH(2)O (4), [Sr(H2O)(6)](n)center dot n[Ni(pydc)(2)(H2O)(2)]center dot 2nH(2)O (5), [NiSr2(pydc)(3)(H2O)(8)](n)center dot 2nH(2)O (6), [ZnSr(pydc)(2)(H2O)(5)](n) (7) and [ZnSr2(pydc)(3)(H2O)(10)](n)center dot 2nH(2)O (8), have been prepared and characterized. The structures of the complexes could be controlled via rationally choosing the appropriate metal salts, adding the starting materials in different orders, and tuning the ratio of the starting materials. Eight varieties of structures, ranging from 1-D chains to 3-D networks, were obtained. The magnetic properties of 2, 3 and 6 were investigated from 2 K to 300 K. Antiferromagnetic M-II center dot center dot center dot M-II interactions were found for 2 and 6, and ferromagnetic interactions were determined for 3. The solid state luminescent properties of 1, 7 and 8 were also studied. |
| WOS关键词 | CRYSTAL-STRUCTURE ; HYDROTHERMAL SYNTHESIS ; MAGNETIC-PROPERTIES ; ORGANIC FRAMEWORKS ; METAL-COMPLEXES ; LUMINESCENT ; CHAIN ; LANTHANIDE ; PHOTOLUMINESCENCE ; DIVERSITY |
| WOS研究方向 | Chemistry ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000329991900018 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5724]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Yanmei,She, Shixiong,Gao, Qian,et al. Synthesis, structures and properties of the first series of Sr-II-M-II (M = Cu, Co, Ni and Zn) coordination polymers based on pyridine-2,5-dicarboxylic acid[J]. CRYSTENGCOMM,2014,16(6):1091-1102. |
| APA | Chen, Yanmei.,She, Shixiong.,Gao, Qian.,Gao, Dandan.,Wang, Derong.,...&Li, Wu.(2014).Synthesis, structures and properties of the first series of Sr-II-M-II (M = Cu, Co, Ni and Zn) coordination polymers based on pyridine-2,5-dicarboxylic acid.CRYSTENGCOMM,16(6),1091-1102. |
| MLA | Chen, Yanmei,et al."Synthesis, structures and properties of the first series of Sr-II-M-II (M = Cu, Co, Ni and Zn) coordination polymers based on pyridine-2,5-dicarboxylic acid".CRYSTENGCOMM 16.6(2014):1091-1102. |
入库方式： OAI收割
来源：青海盐湖研究所
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