Structure of aqueous potassium pentaborate solution
文献类型：期刊论文
| 作者 | Zhu, F. Y.1 ; Fang, C. H.1; Fang, Y.1; Zhou, Y. Q.1; Ge, H. W.1; Liu, H. Y.1,2
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| 刊名 | JOURNAL OF MOLECULAR STRUCTURE
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| 出版日期 | 2015-03-05 |
| 卷号 | 1083页码:471-479 |
| 关键词 | Potassium Pentaborate Solution Structure X-ray Scattering Density Function Theory |
| 文献子类 | Article |
| 英文摘要 | The structure of aqueous potassium pentaborate solution has been confirmed by species distribution calculation, synchrotron X-ray scattering, density function theory calculation. The kinds of species and the transformation relationship were investigated by species distribution calculation. The radial distribution function and the structure parameters were given out by synchrotron X-ray scattering experiment. The hydration distance of K-O(H2O) is similar to 0.294 nm with a average hydration number of 8.0. The B-O(H2O) distance in hydrated anion [B3O3(OH)(4)(H2O)(n)](-) were determined to be similar to 0.37 nm with the hydration number of 4-5. The structure and interaction energy of the first hydration sphere of [K(H2O)(n)](+) and [B3O3(OH)(4)(H2O)(n)](-) were also studied by density functional theory calculation. (C) 2014 Elsevier B.V. All rights reserved. |
| WOS关键词 | TETRABORATE SOLUTIONS ; DFT ; TEMPERATURE ; RAMAN |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000348879500060 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5743]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源与化学实验室 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Chinese Acad Sci, Inst Salt Lakes, Key Lab Salt Resources & Chem, Xining 8100084, Qinghai, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, F. Y.,Fang, C. H.,Fang, Y.,et al. Structure of aqueous potassium pentaborate solution[J]. JOURNAL OF MOLECULAR STRUCTURE,2015,1083:471-479. |
| APA | Zhu, F. Y.,Fang, C. H.,Fang, Y.,Zhou, Y. Q.,Ge, H. W.,&Liu, H. Y..(2015).Structure of aqueous potassium pentaborate solution.JOURNAL OF MOLECULAR STRUCTURE,1083,471-479. |
| MLA | Zhu, F. Y.,et al."Structure of aqueous potassium pentaborate solution".JOURNAL OF MOLECULAR STRUCTURE 1083(2015):471-479. |
入库方式： OAI收割
来源：青海盐湖研究所
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