Studies on enthalpy of solution for ionic liquid: The system of 1-methyl-3-ethylimidazolium tetrafluoroborate (EMIBF4)
文献类型：期刊论文
| 作者 | Yang, Jia-Zhen; Zhang, Zhi-Heng; Fang, Da-Wei; Li, Ji-Guang; Guan, Wei; Tong, Jian |
| 刊名 | FLUID PHASE EQUILIBRIA
 |
| 出版日期 | 2006-09-15 |
| 卷号 | 247期号:1-2页码:80-83 |
| 关键词 | Ionic Liquid Isoperibol Calorimeter Solution Enthalpy Hydration Heat Emibf4 |
| 文献子类 | Article |
| 英文摘要 | The molar solution enthalpies of ionic liquids (IL) EMIBF4 (1-methyl-3-ethylimidazolium tetrafluoroborate), EMIC (1-methyl-3-ethylimidazolium chloride) and ionic solid NaBF4 at various molalities were determined by the solution-reaction isoperibol calorimeter in water at 298.15 K. In terms of a Debye-Huckel limiting term, the molar solution enthalpies of EMIBF4, EMIC and NaBF4 at infinite dilution, A, H, were obtained. Then the values of apparent relative molar enthalpy were calculated. Hydration heat of both cation EMI+ and anion BF4- was discussed. In terms of values of Delta H-s(m)degrees, the reaction heat of NaBF4 + EMIC ->. EMIBF4 + NaCl was estimated. (c) 2006 Elsevier B.V. All rights reserved. |
| WOS关键词 | THERMODYNAMIC PROPERTIES ; AQUEOUS-SOLUTION ; AMINO-ACIDS ; WATER ; CHLORIDE ; CALORIMETER ; DENSITY ; LATTICE |
| WOS研究方向 | Thermodynamics ; Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000240563000010 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5764]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Liaoning Univ, Dept Chem, Shenyang 110036, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Jia-Zhen,Zhang, Zhi-Heng,Fang, Da-Wei,et al. Studies on enthalpy of solution for ionic liquid: The system of 1-methyl-3-ethylimidazolium tetrafluoroborate (EMIBF4)[J]. FLUID PHASE EQUILIBRIA,2006,247(1-2):80-83. |
| APA | Yang, Jia-Zhen,Zhang, Zhi-Heng,Fang, Da-Wei,Li, Ji-Guang,Guan, Wei,&Tong, Jian.(2006).Studies on enthalpy of solution for ionic liquid: The system of 1-methyl-3-ethylimidazolium tetrafluoroborate (EMIBF4).FLUID PHASE EQUILIBRIA,247(1-2),80-83. |
| MLA | Yang, Jia-Zhen,et al."Studies on enthalpy of solution for ionic liquid: The system of 1-methyl-3-ethylimidazolium tetrafluoroborate (EMIBF4)".FLUID PHASE EQUILIBRIA 247.1-2(2006):80-83. |
入库方式： OAI收割
来源：青海盐湖研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。