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Thermo-chemical properties of aqueous solution containing ionic liquids 1. The heat of reaction mixed 1-methyl-3-butylimidazolium chloride with InCl3
文献类型:期刊论文
作者 | Guan, W; Yang, HZ; Li, L; Wang, H; Zhang, QG |
刊名 | FLUID PHASE EQUILIBRIA
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出版日期 | 2006-01-31 |
卷号 | 239期号:2页码:161-165 |
关键词 | Isoperibol Calorimeter Solution Enthalpy Pitzer's Theory Reaction Enthalpy Ionic Liquid Bmiincl4 |
文献子类 | Article |
英文摘要 | The ionic liquid BMIInCl4 was prepared by mixing 1-methyl-3-butylimidazolium chloride (BMIC) with InCl3. The molar solution enthalpies of BMIC and BMIInCl4 at various molalities were determined by the solution reaction isoperibol calorimeter in water at 298.15 K. In terms of Pitzer's electrolyte solution theory, the molar solution enthalpy of BMIC and BMIInCl4 at infinite dilution, Delta(s)H(m)degrees and the parameters: beta(MX)((0)L), beta(MX)((1)L) and C-MX(phi L) were obtained. Then the values of apparent relative molar enthalpy OL and relative partial molar enthalpies of solute (BMIC and BMIInCl4), L-2, were calculated, respectively. In terms of values of Delta(s)H(m)degrees of BMIC, BMIInCl4 and InCl3, the enthalpy change for the reaction: BMIC + InCl3 -> BMIInCl4 was obtained. (c) 2005 Elsevier B.V. All rights reserved. |
WOS关键词 | THERMODYNAMICS ; ENTHALPY ; WATER |
WOS研究方向 | Thermodynamics ; Chemistry ; Engineering |
语种 | 英语 |
WOS记录号 | WOS:000234931000005 |
源URL | [http://ir.isl.ac.cn/handle/363002/5770] ![]() |
专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
作者单位 | 1.Liaoning Univ, Coll Environm Sci, Shenyang 110036, Peoples R China 2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Guan, W,Yang, HZ,Li, L,et al. Thermo-chemical properties of aqueous solution containing ionic liquids 1. The heat of reaction mixed 1-methyl-3-butylimidazolium chloride with InCl3[J]. FLUID PHASE EQUILIBRIA,2006,239(2):161-165. |
APA | Guan, W,Yang, HZ,Li, L,Wang, H,&Zhang, QG.(2006).Thermo-chemical properties of aqueous solution containing ionic liquids 1. The heat of reaction mixed 1-methyl-3-butylimidazolium chloride with InCl3.FLUID PHASE EQUILIBRIA,239(2),161-165. |
MLA | Guan, W,et al."Thermo-chemical properties of aqueous solution containing ionic liquids 1. The heat of reaction mixed 1-methyl-3-butylimidazolium chloride with InCl3".FLUID PHASE EQUILIBRIA 239.2(2006):161-165. |
入库方式: OAI收割
来源:青海盐湖研究所
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