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Thermo-chemical properties of aqueous solution containing ionic liquids 1. The heat of reaction mixed 1-methyl-3-butylimidazolium chloride with InCl3

文献类型:期刊论文

作者Guan, W; Yang, HZ; Li, L; Wang, H; Zhang, QG
刊名FLUID PHASE EQUILIBRIA
出版日期2006-01-31
卷号239期号:2页码:161-165
关键词Isoperibol Calorimeter Solution Enthalpy Pitzer's Theory Reaction Enthalpy Ionic Liquid Bmiincl4
文献子类Article
英文摘要The ionic liquid BMIInCl4 was prepared by mixing 1-methyl-3-butylimidazolium chloride (BMIC) with InCl3. The molar solution enthalpies of BMIC and BMIInCl4 at various molalities were determined by the solution reaction isoperibol calorimeter in water at 298.15 K. In terms of Pitzer's electrolyte solution theory, the molar solution enthalpy of BMIC and BMIInCl4 at infinite dilution, Delta(s)H(m)degrees and the parameters: beta(MX)((0)L), beta(MX)((1)L) and C-MX(phi L) were obtained. Then the values of apparent relative molar enthalpy OL and relative partial molar enthalpies of solute (BMIC and BMIInCl4), L-2, were calculated, respectively. In terms of values of Delta(s)H(m)degrees of BMIC, BMIInCl4 and InCl3, the enthalpy change for the reaction: BMIC + InCl3 -> BMIInCl4 was obtained. (c) 2005 Elsevier B.V. All rights reserved.
WOS关键词THERMODYNAMICS ; ENTHALPY ; WATER
WOS研究方向Thermodynamics ; Chemistry ; Engineering
语种英语
WOS记录号WOS:000234931000005
源URL[http://ir.isl.ac.cn/handle/363002/5770]  
专题青海盐湖研究所_青海盐湖研究所知识仓储
中国科学院青海盐湖研究所
作者单位1.Liaoning Univ, Coll Environm Sci, Shenyang 110036, Peoples R China
2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Guan, W,Yang, HZ,Li, L,et al. Thermo-chemical properties of aqueous solution containing ionic liquids 1. The heat of reaction mixed 1-methyl-3-butylimidazolium chloride with InCl3[J]. FLUID PHASE EQUILIBRIA,2006,239(2):161-165.
APA Guan, W,Yang, HZ,Li, L,Wang, H,&Zhang, QG.(2006).Thermo-chemical properties of aqueous solution containing ionic liquids 1. The heat of reaction mixed 1-methyl-3-butylimidazolium chloride with InCl3.FLUID PHASE EQUILIBRIA,239(2),161-165.
MLA Guan, W,et al."Thermo-chemical properties of aqueous solution containing ionic liquids 1. The heat of reaction mixed 1-methyl-3-butylimidazolium chloride with InCl3".FLUID PHASE EQUILIBRIA 239.2(2006):161-165.

入库方式: OAI收割

来源:青海盐湖研究所

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