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Studies on the thermodynamic properties of the ionic liquid BMIGaCl4
文献类型：期刊论文
| 作者 | Xu, WG; Lu, XM; Zhang, QG; Gui, JS; Yang, JZ |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2006-03-01 |
| 卷号 | 24期号:3页码:331-335 |
| 关键词 | Ionic Liquid Density Surface Tension Gallium Chloride Raman Spectrum Ab Initio Calculation |
| 文献子类 | Article |
| 英文摘要 | An ionic liquid (IL) BMIGaCl4 was prepared by directly mixing GaCl3 and 1-methyl-3-butylimidazolium chloride with molar ratio of 1/1 under argon atmosphere. The densities and surface tensions of this pure ionic liquid were determined in the temperature range of 268.15 to (338.15 +/- 0.1) K. A new theoretical model of ionic liquids, an interstice model, was applied to calculate the thermal expansion coefficient of IL BMIGaCl4, a, and the magnitude order of its value calculated by the theory was the same as experimental one. Both Raman scattering and ab initio calculations indicate that GaCl4- is the only species containing Ga in the ionic liquid BMIGaCl4. |
| WOS关键词 | 1-METHYL-3-BUTYLIMIDAZOLIUM CHLORIDE ; LATTICE ENERGIES ; CRYSTALS ; SOLVENTS ; DENSITY ; VOLUME |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000235990900008 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5771]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China 2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China 3.Shenyang Normal Univ, Dept Chem, Liaoning 110032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, WG,Lu, XM,Zhang, QG,et al. Studies on the thermodynamic properties of the ionic liquid BMIGaCl4[J]. CHINESE JOURNAL OF CHEMISTRY,2006,24(3):331-335. |
| APA | Xu, WG,Lu, XM,Zhang, QG,Gui, JS,&Yang, JZ.(2006).Studies on the thermodynamic properties of the ionic liquid BMIGaCl4.CHINESE JOURNAL OF CHEMISTRY,24(3),331-335. |
| MLA | Xu, WG,et al."Studies on the thermodynamic properties of the ionic liquid BMIGaCl4".CHINESE JOURNAL OF CHEMISTRY 24.3(2006):331-335. |
入库方式： OAI收割
来源：青海盐湖研究所
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