Thermochemistry of dicesium calcium tetraborate octahydrate
文献类型：期刊论文
| 作者 | Zhu Lixia; Yue Tao; Gao Shiyang |
| 刊名 | THERMOCHIMICA ACTA
 |
| 出版日期 | 2006-09-01 |
| 卷号 | 448期号:1页码:66-68 |
| 关键词 | Cs2ca[B4o5(Oh)(4)](2)Center Dot 8h(2)o Standard Molar Enthalpy Of Formation Solution Calorimetry Molar Enthalpy Of Solution Aqueous Hydrochloric Acid Solution |
| 文献子类 | Article |
| 英文摘要 | The enthalpies of solution of Cs2Ca[B4O5(OH)(4)](2)center dot 8H(2)O(s) in approximately 1 mol dm(-3) aqueous hydrochloric acid and of CsCl(s) in aqueous (hydrochloric acid + boric acid + calcium oxide) were determined. From these results and the enthalpies of solution of H3BO3(s) in approximately 1 mol dm(-3) HCl(aq) and of CaO(s) in aqueous (hydrochloric acid + boric acid), the standard molar enthalpy of formation of -(10328 +/- 6) kJ mol(-1) for Cs2Ca[B4O5(OH)(4)](2)center dot 8H(2)O(s) was obtained from the standard molar enthalpy of formation of CaO(S), CsCl(s), H3BO3(s) and H2O(l). The standard molar entropy of formation of Cs2Ca[B4O5(OH)(4)](2)center dot 8H(2)O(s) was calculated from the thermodynamic relation with the standard molar Gibbs free energy of formation of Cs2Ca[B4O5(OH)(4)](2)center dot 8H(2)O(s) computed from a group contribution method. (c) 2006 Elsevier B.V. All rights reserved. |
| WOS关键词 | NONLINEAR-OPTICAL CRYSTAL ; CESIUM LITHIUM BORATE ; OCTABORATE DODECAHYDRATE ; CSLIB6O10 |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000240359900014 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5777]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Xidian Univ, Sch Sci, Xian 710071, Peoples R China 2.Acad Sinica, Inst Salt Lakes, Xian Branch, Xian 710043, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu Lixia,Yue Tao,Gao Shiyang. Thermochemistry of dicesium calcium tetraborate octahydrate[J]. THERMOCHIMICA ACTA,2006,448(1):66-68. |
| APA | Zhu Lixia,Yue Tao,&Gao Shiyang.(2006).Thermochemistry of dicesium calcium tetraborate octahydrate.THERMOCHIMICA ACTA,448(1),66-68. |
| MLA | Zhu Lixia,et al."Thermochemistry of dicesium calcium tetraborate octahydrate".THERMOCHIMICA ACTA 448.1(2006):66-68. |
入库方式： OAI收割
来源：青海盐湖研究所
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