Studies on properties of ionic liquid EMIFeCl4 based on transition metal
文献类型：期刊论文
| 作者 | Zhang, QG; Guang, W; Tong, J; Jin, ZX |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2006-05-10 |
| 卷号 | 27期号:5页码:925-928 |
| 关键词 | Ionic Liquid Density Surface Tension Fecl3 Interstice Model |
| 文献子类 | Article |
| 英文摘要 | An ionic liquid(IL) EMIFeCl4 was prepared by directly mixing FeCl3 and 1-methyl-3-ethylimidazolium chloride with a molar ratio 1/1 under dry argon atmosphere. The densities, and surface tension of the pure IL were determined in the temperature range from 293.15 K to (343.15 +/- 0.1) K. The properties for the ionic liquids were discussed by using Glasser's theory. The crystal energy of ionic liquid is Much lower than ionic solid and this is the underlying reason for forming ionic liquid at room temperature. In addition, a I new theoretical model of ionic liquid, that is interstice model, was applied to calculating the thermal expansion coefficient of EMIFeCl4. And the magnitude order of the thermal expansion coefficient, alpha, calculated by the theoretical model is in good agreement with experimental value. The result shows that there is much reasonableness for the interstice model of ionic liquid. |
| WOS关键词 | ROOM-TEMPERATURE ; THERMODYNAMICS ; CHLORIDE ; SOLVENTS ; LATTICE ; FECL3 |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000237792700033 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5783]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Bohai Univ, Coll Chem & Chem Engn, Jinzhou 121013, Peoples R China 2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, QG,Guang, W,Tong, J,et al. Studies on properties of ionic liquid EMIFeCl4 based on transition metal[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2006,27(5):925-928. |
| APA | Zhang, QG,Guang, W,Tong, J,&Jin, ZX.(2006).Studies on properties of ionic liquid EMIFeCl4 based on transition metal.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,27(5),925-928. |
| MLA | Zhang, QG,et al."Studies on properties of ionic liquid EMIFeCl4 based on transition metal".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 27.5(2006):925-928. |
入库方式： OAI收割
来源：青海盐湖研究所
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