Studies on the thermochemisry for scattered metal compound InCl3
文献类型：期刊论文
| 作者 | Guan, W; Li, L; Wang, H; Xu, WG; Yang, JZ |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2006-02-10 |
| 卷号 | 27期号:2页码:310-313 |
| 关键词 | Solution Enthalpy Pitzer's Theory Isoperibol Calorimeter Electrolyte Solution Incl3 HydratIon Heat Of Ion |
| 文献子类 | Article |
| 英文摘要 | The molar solution enthalpies of scattered metal compound InCl3 with various molalities were determined at 298.150 K in water by the solution reaction isoperibol calorimeter. According to Pitzer's electrolyte solution theory, the molar solution enthalpy of InCl3 at infinite dilution, Delta(s)H(m)(infinity), and Pitzer's parameters beta(MX)((0)L) and beta(MX)((1)L) were obtianed. Then the values of apparent relative molar enthalpy Phi(L), hydration heat and relative partial molar enthalpy of solute(InCl3), (L) over bar (2), were calculated, respectively. At last, the interaction of InCl3 with water was discussed. In terms of the crystal lattice energy of InCl3 and the hydration heat of Cl-, the values of the hydration heat of InCl3 and In3+ were obtained. |
| WOS关键词 | ION-PAIR ; THERMODYNAMICS ; SYSTEM ; HCL+GACL3+H2O ; 55-DEGREES-C ; CALORIMETER |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000235414300025 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5796]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Liaoning Univ, Coll Environm & Life Sci, Shenyang 110036, Peoples R China 2.Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China 3.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guan, W,Li, L,Wang, H,et al. Studies on the thermochemisry for scattered metal compound InCl3[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2006,27(2):310-313. |
| APA | Guan, W,Li, L,Wang, H,Xu, WG,&Yang, JZ.(2006).Studies on the thermochemisry for scattered metal compound InCl3.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,27(2),310-313. |
| MLA | Guan, W,et al."Studies on the thermochemisry for scattered metal compound InCl3".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 27.2(2006):310-313. |
入库方式： OAI收割
来源：青海盐湖研究所
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