热门
Study of the volumetric properties of the aqueous ionic liquid 1-methyl-3-pentylimidazolium tetrafluoroborate
文献类型：期刊论文
| 作者 | Yang, Jia-Zhen; Tong, Jing; Li, Jing-Bin |
| 刊名 | JOURNAL OF SOLUTION CHEMISTRY
 |
| 出版日期 | 2007-05-01 |
| 卷号 | 36期号:5页码:573-582 |
| 关键词 | Volumetric Properties Ionic Liquid [Pmim][Bf4] Pitzer's Equation |
| 文献子类 | Article |
| 英文摘要 | This paper reports the densities of aqueous solutions of the ionic liquid (IL) 1-methyl-3-pentylimidazolium tetrafluoroborate ([pmim][BF4]) that were measured from 278.15 to 343.15 K, at intervals of 5 K, using an Anton Parr model DMA 4500 oscillating U-tube densitometer. The apparent molar volume, phi V-B, and the partial molar volume of [pmim] [BF4], V-B, were calculated. The values of the apparent molar volume, phi V-B, were fitted to Pitzer's model for volumetric properties by the method of least-squares, which allowed the partial molar volume of the IL at infinite dilution, V-B(o), and Pitzer's parameters, ss((0)V)(M,X) and ss(M,X),((1)V) to be obtained. The small standard deviations of the fits show that Pitzer's model is also appropriate for representing the volumetric properties of aqueous solutions of the ionic liquid [pmim][[BF4]. |
| WOS关键词 | THERMODYNAMICS ; ELECTROLYTES ; COEFFICIENTS ; SOLVENT |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000247033000002 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5822]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China 2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Jia-Zhen,Tong, Jing,Li, Jing-Bin. Study of the volumetric properties of the aqueous ionic liquid 1-methyl-3-pentylimidazolium tetrafluoroborate[J]. JOURNAL OF SOLUTION CHEMISTRY,2007,36(5):573-582. |
| APA | Yang, Jia-Zhen,Tong, Jing,&Li, Jing-Bin.(2007).Study of the volumetric properties of the aqueous ionic liquid 1-methyl-3-pentylimidazolium tetrafluoroborate.JOURNAL OF SOLUTION CHEMISTRY,36(5),573-582. |
| MLA | Yang, Jia-Zhen,et al."Study of the volumetric properties of the aqueous ionic liquid 1-methyl-3-pentylimidazolium tetrafluoroborate".JOURNAL OF SOLUTION CHEMISTRY 36.5(2007):573-582. |
入库方式： OAI收割
来源：青海盐湖研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。