Study on solution enthalpies of ionic liquids of C3MIBF4 and C5MIBF4
文献类型：期刊论文
| 作者 | Fang Da-Wei1,2; Sun Ying-Chun1; Li Ji-Guang1; Wang Zhen-Wei1; Yang Jia-Zhen1 |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2008-02-28 |
| 卷号 | 66期号:4页码:408-412 |
| 关键词 | Ionic Liquid Isoperibol Calorimeter Solution Enthalpy Pitzer's Theory Hydration Enthalpy Of Cation |
| 文献子类 | Article |
| 英文摘要 | The molar enthalpies of dissolution (Delta H-s(m)) of ionic liquids C3MIBF4 (1-methyl-3-propylimidazolium tetrafluoroborate) and C5MIBF4 (1-methyl-3-pentylimidazolium tetrafluoroborate) in water were determined by a solution-reaction isoperibol calorimeter at 298.15 K. According to Pitzer's electrolyte solution theory, the standard molar enthalpy values of solutions of C3MIBF4 and C5MIBF4, Delta H-s(m)circle minus and Pitzer parameters: beta((0)L)(MX) and beta L-(1)(MX), were obtained, respectively. The hydration enthalpies of cations Delta H+ in C5MIBF4 and C3MIBF4 estimated from Glasser's theory of lattice energy were - 171 and -207 kJ circle mol(-1), respectively. |
| WOS关键词 | THERMOCHEMICAL PROPERTIES ; SURFACE-TENSION ; WATER ; TETRAFLUOROBORATE ; THERMODYNAMICS ; CHLORIDE ; DENSITY |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000254396700002 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5846]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Liaoning Univ, Coll Chem, Inst Rare & Scattered Elements, Shenyang 110036, Peoples R China 2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fang Da-Wei,Sun Ying-Chun,Li Ji-Guang,et al. Study on solution enthalpies of ionic liquids of C3MIBF4 and C5MIBF4[J]. ACTA CHIMICA SINICA,2008,66(4):408-412. |
| APA | Fang Da-Wei,Sun Ying-Chun,Li Ji-Guang,Wang Zhen-Wei,&Yang Jia-Zhen.(2008).Study on solution enthalpies of ionic liquids of C3MIBF4 and C5MIBF4.ACTA CHIMICA SINICA,66(4),408-412. |
| MLA | Fang Da-Wei,et al."Study on solution enthalpies of ionic liquids of C3MIBF4 and C5MIBF4".ACTA CHIMICA SINICA 66.4(2008):408-412. |
入库方式： OAI收割
来源：青海盐湖研究所
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