Lewis acid catalyzed intermolecular olefin hydroamination: Scope, limitation, and mechanism
文献类型：期刊论文
| 作者 | Cheng, Xiaojuan1; Xia, Yuanzhi1,2; Wei, Hua1; Xu, Bin2; Zhang, Chongguang1; Li, Yahong1,2,3; Qian, Guimin2 ; Zhang, Xiaohua1; Li, Kai1; Li, Wu2
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| 刊名 | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
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| 出版日期 | 2008-04-01 |
| 期号 | 11页码:1929-1936 |
| 关键词 | Hydroamination Lewis Acids Amines Catalysis Mechanisms |
| 文献子类 | Article |
| 英文摘要 | Intermolecular olefin hydroamination was studied by various Lewis acids. The results of ZrCl(4), FeCl(3), BiCl(3), and AlCl(3) catalyzed reactions of norbornene with aromatic amines were compared, and BiCl(3) was found to be the most effective catalyst to give high yields for various amines, whereas ZrCl(4) could promote the reactions at relatively low temperatures. The FeCl(3) catalyzed reactions were the most chemoselective and excellent yields could be achieved for certain amines by using AlCl(3). A carbocation mechanism was proposed, and the controllable syntheses of allylamine and tetrahydroquinoline from isoprene and 2,5-dichloroaniline were achieved by application of this mechanism. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008). |
| WOS关键词 | INTRAMOLECULAR HYDROAMINATION ; ASYMMETRIC HYDROAMINATION ; BRONSTED ACID ; STEREOSELECTIVE-SYNTHESIS ; HYDROARYLATION REACTIONS ; VINYLSILANES BEARING ; UNACTIVATED OLEFINS ; CARBOXYLIC-ACIDS ; IONIC SOLVENTS ; AMINO GROUP |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000255144100010 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5865]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源综合利用工程技术中心 |
| 作者单位 | 1.Suzhou Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem & Chem Engn, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheng, Xiaojuan,Xia, Yuanzhi,Wei, Hua,et al. Lewis acid catalyzed intermolecular olefin hydroamination: Scope, limitation, and mechanism[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2008(11):1929-1936. |
| APA | Cheng, Xiaojuan.,Xia, Yuanzhi.,Wei, Hua.,Xu, Bin.,Zhang, Chongguang.,...&Li, Wu.(2008).Lewis acid catalyzed intermolecular olefin hydroamination: Scope, limitation, and mechanism.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(11),1929-1936. |
| MLA | Cheng, Xiaojuan,et al."Lewis acid catalyzed intermolecular olefin hydroamination: Scope, limitation, and mechanism".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .11(2008):1929-1936. |
入库方式： OAI收割
来源：青海盐湖研究所
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