Pyrazolato-bridged 1-D Co(II) coordination polymer and dinuclear Ni(II) and Cu(II) complexes: Syntheses, crystal structures and magnetic properties
文献类型：期刊论文
| 作者 | Zhang, Su-Yun1; Li, Yahong1,2; Li, Wu2
|
| 刊名 | INORGANICA CHIMICA ACTA
 |
| 出版日期 | 2009-05-15 |
| 卷号 | 362期号:7页码:2247-2252 |
| 关键词 | 1-d Chain Complex Dinuclear Complexes Syntheses Structures Magnetic Properties |
| 文献子类 | Article |
| 英文摘要 | Three complexes of composition [Co(3)(Hdcp)(2)(phen)(3)(H(2)O)(2)](n) center dot nH(2)O (1), [Ni(2)(Hdcp)(2)(H(2)O)(4)](Im)(2) (2) and [Cu(2)(Hpca)(2)(H(2)O)(2)(Im)(2)] (3) (H(3)dcp = 3,5-pyrazoledicarboxylic acid, H(2)pca = 1H-pyrazole-5-carboxylic acid, Im = imidazole and phen = 1,10-phenanthroline) have been synthesized via hydrothermal reactions and their structures have been characterized. Complex 1 is mainly constructed by Hdcp and ancillary ligand 1,10-phenanthroline and exhibits one-dimensional linear chain structure. Complexes 2 and 3 are pyrazolato-bridged dinuclear complexes. The ancillary imidazole ligand was not involved in the coordination and stacked to the lattice of the complex in 2. In the process of synthesis 3, imidazole ligand was coordinated to the metal centre; with one of the carboxylic group of the H(3)dcp ligand was eliminated to form [Cu(2)(Hpca)(2)(H(2)O)(2)(Im)(2)] (3) in situ. The results of magnetic susceptibility measurements indicate that there exist antiferromagnetic interactions between Co(II)and Ni(II) centres in compounds 1 and 2, respectively. (c) 2008 Elsevier B.V. All rights reserved. |
| WOS关键词 | SINGLE-CHAIN MAGNET ; BUILDING-BLOCK ; COBALT(II) ; LIGAND ; CLUSTER ; NICKEL(II) ; COMPOUND ; BEHAVIOR ; SPIN ; FRAMEWORKS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000265467300021 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5878]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源综合利用工程技术中心 |
| 作者单位 | 1.Suzhou Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Su-Yun,Li, Yahong,Li, Wu. Pyrazolato-bridged 1-D Co(II) coordination polymer and dinuclear Ni(II) and Cu(II) complexes: Syntheses, crystal structures and magnetic properties[J]. INORGANICA CHIMICA ACTA,2009,362(7):2247-2252. |
| APA | Zhang, Su-Yun,Li, Yahong,&Li, Wu.(2009).Pyrazolato-bridged 1-D Co(II) coordination polymer and dinuclear Ni(II) and Cu(II) complexes: Syntheses, crystal structures and magnetic properties.INORGANICA CHIMICA ACTA,362(7),2247-2252. |
| MLA | Zhang, Su-Yun,et al."Pyrazolato-bridged 1-D Co(II) coordination polymer and dinuclear Ni(II) and Cu(II) complexes: Syntheses, crystal structures and magnetic properties".INORGANICA CHIMICA ACTA 362.7(2009):2247-2252. |
入库方式： OAI收割
来源：青海盐湖研究所
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