Liquid-solid metastable phase equilibria for the quaternary system (NaCl-KCl-CaCl2-H2O) at 308.15 K
文献类型：期刊论文
| 作者 | Li, D. C.1,2; Deng, T. L.1,2 |
| 刊名 | JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
 |
| 出版日期 | 2009-02-01 |
| 卷号 | 95期号:2页码:361-367 |
| 关键词 | Metastable Phase Equilibrium Pitzer Parameters Solubility |
| 文献子类 | Article |
| 英文摘要 | The solubility and the physicochemical properties (densities, viscosities, refractive indices, conductivities and pH) in the liquid-solid metastable system (NaCl-KCl-CaCl2-H2O) at 308.15 K have been investigated using the isothermal evaporation method, and the dry-salt phase diagram, water-phase diagram, and the diagram of physicochemical properties vs. composition in the system were plotted. One three-salt cosaturated point, three metastable solubility isotherm curves, and three crystallization regions corresponding to sodium chloride, potassium chloride and calcium chloride tetrahydrate were formed, and neither solid solution nor double salts were found. On the basis of the extended Harvie-Weare (HW) model and its temperature-dependent equation, the values of the Pitzer parameters beta((0)), beta((1)), C-phi for NaCl, KCl and CaCl2, the mixing ion-interaction parameters theta(Na,K), theta(Na,Ca), theta(K,Ca), I-Na,I-K,I-Cl, I-Na,I-Ca,I-Cl, I-K,I-Ca,I-Cl, and the Debye-Huckel parameter A(phi) and the chemical potentials of the minerals in the quaternary system at 308.15 K were fitted, and the predictive solubility based on the temperature-dependent equation and the chemical potentials of the minerals agrees well with the experimental data. |
| WOS关键词 | MINERAL SOLUBILITIES ; NATURAL-WATERS ; PREDICTION ; MODEL ; 25-DEGREES-C ; THERMODYNAMICS ; TEMPERATURES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000264133800005 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5900]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Chengdu Univ Sci & Technol, Coll Mat Chem & Chem Engn, Chengdu 610059, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, D. C.,Deng, T. L.. Liquid-solid metastable phase equilibria for the quaternary system (NaCl-KCl-CaCl2-H2O) at 308.15 K[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2009,95(2):361-367. |
| APA | Li, D. C.,&Deng, T. L..(2009).Liquid-solid metastable phase equilibria for the quaternary system (NaCl-KCl-CaCl2-H2O) at 308.15 K.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,95(2),361-367. |
| MLA | Li, D. C.,et al."Liquid-solid metastable phase equilibria for the quaternary system (NaCl-KCl-CaCl2-H2O) at 308.15 K".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 95.2(2009):361-367. |
入库方式： OAI收割
来源：青海盐湖研究所
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