Synthesis, Crystal Structure of (NH3CH2CHNH2CH3)(3)[(WO2)-O-VI-(OC6H4O)(2)] and Its NMR Studies on the Interaction with ATP
文献类型：期刊论文
| 作者 | Song Fugen1,2 ; Lu Xiaoming1; Yu Chong1; Shi Xudong1; Chen Yuyou1; Bi Yangang1; Chi Zixiang1; Ye Chaohui3
|
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2009-06-14 |
| 卷号 | 67期号:11页码:1195-1200 |
| 关键词 | Biomimetic Complex Of The cOfactor Of Tungstoenzyme Crystal Structure Atp H-1 Nmr |
| 文献子类 | Article |
| 英文摘要 | Cis-dioxo-catecholatotungsten (VI) complex (NH3CH2CHNH2CH3)(2)[(WO2)-O-VI(OC6H4O)(2)] is obtained with chiral protonated 1,2-propanediamine by the reaction of tetrabutyl ammonium decatungstate with catechol in the mixed solvent of CH3OH, CH3CN at room temperature. The crystal structure of complex was determined by X-ray diffraction structural analysis. The results show that complex belongs to monoclinic system with space group P2(1)/n, a=1.1099(3) nm, b=1.0416(3) nm, c=1.8874(6) nm, beta=96.492(6)degrees, V=2.1679(11) nm(3), z=4, R-1=0.0445, wR(2)=0.0682; and Studied by IR, H-1 NMR and UV-Vis. The NMR studies on the interaction of the title complex with adenosine-triphosphate(ATP) reveal that H-1 chemical shifts of 1,2-propanediamine and catechol with and without ATP exhibit distinct difference, the reduction of W(VI) to W(V) occurs when the title complex is dissolved in D2O and the W(V) is oxidized again when ATP solution is mixed with original solution and the hydrolysis of the catecholato ligand take places at mean time being monitored by H-1 NMR. |
| WOS关键词 | OXO TRANSFER ; REACTIVITY ; TUNGSTEN ; MOLYBDOPTERIN ; MOLYBDENUM ; SITES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000267606400007 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5906]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源综合利用工程技术中心 |
| 作者单位 | 1.Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China 3.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song Fugen,Lu Xiaoming,Yu Chong,et al. Synthesis, Crystal Structure of (NH3CH2CHNH2CH3)(3)[(WO2)-O-VI-(OC6H4O)(2)] and Its NMR Studies on the Interaction with ATP[J]. ACTA CHIMICA SINICA,2009,67(11):1195-1200. |
| APA | Song Fugen.,Lu Xiaoming.,Yu Chong.,Shi Xudong.,Chen Yuyou.,...&Ye Chaohui.(2009).Synthesis, Crystal Structure of (NH3CH2CHNH2CH3)(3)[(WO2)-O-VI-(OC6H4O)(2)] and Its NMR Studies on the Interaction with ATP.ACTA CHIMICA SINICA,67(11),1195-1200. |
| MLA | Song Fugen,et al."Synthesis, Crystal Structure of (NH3CH2CHNH2CH3)(3)[(WO2)-O-VI-(OC6H4O)(2)] and Its NMR Studies on the Interaction with ATP".ACTA CHIMICA SINICA 67.11(2009):1195-1200. |
入库方式： OAI收割
来源：青海盐湖研究所
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