Synthesis, Structural Characterization, and Catalytic Activity of Scandium, Samarium, and Dysprosium Complexes Supported by Tris(pyrrolyl-alpha-methyl)amine Ligand
文献类型：期刊论文
| 作者 | Zhou, Fengying1; Wu, Jing1; Lin, Miaoshui1; Zhao, Yang1; Wu, Jian1; Zhang, Yong1; Li, Wu2 ; Li, Yahong1,2,3
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| 刊名 | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
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| 出版日期 | 2011 |
| 卷号 | 637期号:1页码:117-121 |
| 关键词 | Scandium Samarium Dysprosium Polymerization Epsilon-caprolactone |
| 文献子类 | Article |
| 英文摘要 | The synthesis, structures and catalytic activities of three organolanthanide complexes supported by the H(3)tpa ligand (H(3)tpa = tris(pyrrolyl-alpha-methyl) amine) are described. Treatment of H(3)tpa with one equivalent of Ln[N(SiMe3)(2)](3) (Ln = Sc, Sm, Dy) in THF gives, after recrystallization from toluene/THF solution, Sc(tpa)(THF)(2) (1), Sm(tpa)(THF)(3) (2) and Dy(tpa)(THF)(3) (3) in good yields. The structures of complexes 1-3 were determined by single-crystal X-ray diffraction and elemental analysis. Complexes 2 and 3 exhibited good catalytic activity for the polymerization of epsilon-caprolactone. |
| WOS关键词 | POLYBENZIMIDAZOLE TRIPODAL LIGANDS ; ORGANOLANTHANIDE COMPLEXES ; LANTHANIDE COMPLEXES ; EPSILON-CAPROLACTONE ; POLYMERIZATION CATALYSIS ; ALKYL COMPLEXES ; REACTIVITY ; REDUCTION ; COORDINATION ; CHEMISTRY |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000285788600021 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5978]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源综合利用工程技术中心 |
| 作者单位 | 1.Suzhou Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Fengying,Wu, Jing,Lin, Miaoshui,et al. Synthesis, Structural Characterization, and Catalytic Activity of Scandium, Samarium, and Dysprosium Complexes Supported by Tris(pyrrolyl-alpha-methyl)amine Ligand[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2011,637(1):117-121. |
| APA | Zhou, Fengying.,Wu, Jing.,Lin, Miaoshui.,Zhao, Yang.,Wu, Jian.,...&Li, Yahong.(2011).Synthesis, Structural Characterization, and Catalytic Activity of Scandium, Samarium, and Dysprosium Complexes Supported by Tris(pyrrolyl-alpha-methyl)amine Ligand.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,637(1),117-121. |
| MLA | Zhou, Fengying,et al."Synthesis, Structural Characterization, and Catalytic Activity of Scandium, Samarium, and Dysprosium Complexes Supported by Tris(pyrrolyl-alpha-methyl)amine Ligand".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 637.1(2011):117-121. |
入库方式： OAI收割
来源：青海盐湖研究所
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