Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand: Synthesis, Crystal Structure and Magnetic Property
文献类型：期刊论文
| 作者 | Zhao, Yang1; Zhang, Suyun1; Zheng, Lina1; Chen, Yanmei2; Hu, Bin2 ; Li, Yahong1,2
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| 刊名 | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
 |
| 出版日期 | 2011 |
| 卷号 | 637期号:10页码:1304-1307 |
| 关键词 | 2-pyridyloximate Tetranuclear Complexes Manganese Ir Spectroscopy Magnetic Properties |
| 文献子类 | Article |
| 英文摘要 | A tetranuclear manganese complex of the composition {Mn(4)[(Py)C(Ph)NO](4)(CH(3)CH(2)OH)(3)(CH(3)CH(2)O)Cl(3)}center dot 2H(2)O (1) was synthesized by solvothermal reaction, and characterized by X-ray single crystal diffraction, IR spectroscopy, and elemental analysis. X-ray analysis revealed that complex 1 contains a [Mn(4)(NO)(4)](4+) core with three Mn(II) atoms displaying distorted octahedral arrangements and one Mn(II) ion exhibiting a trigonal bipyramidal arrangement. Low-temperature magnetic susceptibility measurement for the solid sample of 1 revealed antiferromagnetic Mn(II)center dot center dot center dot Mn(II) interactions. |
| WOS关键词 | NEUTRON-SCATTERING SPECTRA ; DI-2-PYRIDYL KETONE OXIME ; CARBOXYLATE CHEMISTRY ; COORDINATION CHEMISTRY ; PARTIAL TRANSFORMATION ; ENERGY-LEVELS ; NI-II ; TRINUCLEAR ; DINUCLEAR ; CHAIN |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000294390200007 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/5998]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源与化学实验室 |
| 作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Yang,Zhang, Suyun,Zheng, Lina,et al. Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand: Synthesis, Crystal Structure and Magnetic Property[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2011,637(10):1304-1307. |
| APA | Zhao, Yang,Zhang, Suyun,Zheng, Lina,Chen, Yanmei,Hu, Bin,&Li, Yahong.(2011).Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand: Synthesis, Crystal Structure and Magnetic Property.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,637(10),1304-1307. |
| MLA | Zhao, Yang,et al."Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand: Synthesis, Crystal Structure and Magnetic Property".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 637.10(2011):1304-1307. |
入库方式： OAI收割
来源：青海盐湖研究所
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